Reactivity of a 1:1 copper-oxygen complex: isolation of a Cu(II)-o-iminosemiquinonato species

While a 1:1 Cu-O2 adduct is generally unreactive with organic substrates, phosphines displace O2 via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.

Bibliographische Detailangaben

Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2005-04 (15), p.2014-2016
Hauptverfasser:	Reynolds, Anne M, Lewis, Elizabeth A, Aboelella, Nermeen W, Tolman, William B
Format:	Artikel
Sprache:	eng
Schlagworte:	Cations - chemistry Copper - chemistry Models, Molecular Molecular Conformation Organometallic Compounds - chemistry Organometallic Compounds - isolation & purification Oxygen - chemistry
Online-Zugang:	Volltext
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