Kinetic Study of the ClOO + NO Reaction Using Cavity Ring-Down Spectroscopy

Cavity ring-down spectroscopy was used to study the reaction of ClOO with NO in 50−150 Torr total pressure of O2/N2 diluent at 205−243 K. A value of k(ClOO+NO) = (4.5 ± 0.9) × 10-11 cm3 molecule-1 s-1 at 213 K was determined (quoted uncertainties are two standard deviations). The yield of NO2 in the...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2006-03, Vol.110 (10), p.3546-3551
Hauptverfasser:	Enami, Shinichi, Hoshino, Yosuke, Ito, Yuki, Hashimoto, Satoshi, Kawasaki, Masahiro, Wallington, Timothy J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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