A Stacking Interaction between a Bridging Hydrogen Atom and Aromatic π Density in the n-B18H22-Benzene System

The structures of n‐B18H22 and of n‐B18H22⋅C6H6 were determined by single‐crystal X‐ray analysis at −60 °C. The geometry of the boron cluster itself does not seem to be appreciably affected by solvation. There does, however, appear to be an unusual interaction of a polyborane bridging hydrogen atom...

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Veröffentlicht in:	Chemistry : a European journal 2006-03, Vol.12 (9), p.2571-2578
Hauptverfasser:	Hamilton, Ewan J. M., Kultyshev, Roman G., Du, Bin, Meyers, Edward A., Liu, Shengming, Hadad, Christopher M., Shore, Sheldon G.
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzene - chemistry boranes Boron Compounds - chemistry cluster compounds Crystallography, X-Ray density functional calculations Electrons Hydrocarbons, Aromatic - chemistry Hydrogen - chemistry Hydrogen Bonding NMR spectroscopy pi interactions Solvents X-ray diffraction
Online-Zugang:	Volltext
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