Syntheses, Structures, and Reactivity of Radial Oligocyclopentadienyl Metal Complexes: Penta(ferrocenyl)cyclopentadienyl and Congeners
“Supra”Cp: Fivefold Negishi coupling of pentaiodocymantrene resulted in radial oligocyclopentadienyl metal complexes (see scheme). These complexes show fascinating conformational and chemical behavior, including MM and CpCp bond formation and the liberation of the novel supraligand penta(ferroceny...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2006-03, Vol.45 (11), p.1794-1799 |
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| container_issue | 11 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 45 |
| creator | Yu, Yong Bond, Andrew D. Leonard, Philip W. Vollhardt, K. Peter C. Whitener, Glenn D. |
| description | “Supra”Cp: Fivefold Negishi coupling of pentaiodocymantrene resulted in radial oligocyclopentadienyl metal complexes (see scheme). These complexes show fascinating conformational and chemical behavior, including MM and CpCp bond formation and the liberation of the novel supraligand penta(ferrocenyl)cyclopentadiene. dba=dibenzylideneacetone. |
| doi_str_mv | 10.1002/anie.200504047 |
| format | Article |
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These complexes show fascinating conformational and chemical behavior, including MM and CpCp bond formation and the liberation of the novel supraligand penta(ferrocenyl)cyclopentadiene. dba=dibenzylideneacetone.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.200504047</identifier><identifier>PMID: 16470902</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>carbocations ; cyclopentadienyl ligands ; Ferrous Compounds - chemistry ; metal-metal interactions ; Metallocenes ; Metals - chemistry ; Models, Chemical ; Molecular Conformation ; Molecular Probes - chemistry ; Organometallic Compounds - chemical synthesis ; Organometallic Compounds - chemistry ; Organometallic Compounds - pharmacology ; Oxidation-Reduction ; palladium ; radialenes</subject><ispartof>Angewandte Chemie International Edition, 2006-03, Vol.45 (11), p.1794-1799</ispartof><rights>Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. 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These complexes show fascinating conformational and chemical behavior, including MM and CpCp bond formation and the liberation of the novel supraligand penta(ferrocenyl)cyclopentadiene. dba=dibenzylideneacetone.</description><subject>carbocations</subject><subject>cyclopentadienyl ligands</subject><subject>Ferrous Compounds - chemistry</subject><subject>metal-metal interactions</subject><subject>Metallocenes</subject><subject>Metals - chemistry</subject><subject>Models, Chemical</subject><subject>Molecular Conformation</subject><subject>Molecular Probes - chemistry</subject><subject>Organometallic Compounds - chemical synthesis</subject><subject>Organometallic Compounds - chemistry</subject><subject>Organometallic Compounds - pharmacology</subject><subject>Oxidation-Reduction</subject><subject>palladium</subject><subject>radialenes</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkE1P3DAQhq0KVCjtlSPKCVGJLHYc2wk3tOVL4qsLao-W40zArTfe2k5L_gC_m0S7AiQOPc1o5nnfGb0IbRM8IRhnB6o1MMkwZjjHufiANgnLSEqFoGtDn1OaioKRDfQphF8DXxSYf0QbhOcClzjbRE-3fRsfIEDYT26j73Ts_Nirtk5moHQ0f03sE9ckM1UbZZNra-6d7rV1C2jjMIO2t8klxGE3dfOFhUcIh8nNuNxrwHunR-LrO8l4Yerae2jBh89ovVE2wJdV3UJ3J8d307P04vr0fHp0kWpaEJE2ZaWqQjMuGqgbhWlT5aWGola8ZIWmhFWMEy0gzwTTOSZMa5wzpTjhJXC6hXaXtgvv_nQQopyboMFa1YLrguRCZDQr6ABOlqD2LgQPjVx4M1e-lwTLMXg5Bi9fgh8EOyvnrppD_Yqvkh6Acgn8Mxb6_9jJo6vz47fm6VJrQoTHF63yv4ePqWDy59WpJJffZjdn2Q_5nT4D0dOiWg</recordid><startdate>20060306</startdate><enddate>20060306</enddate><creator>Yu, Yong</creator><creator>Bond, Andrew D.</creator><creator>Leonard, Philip W.</creator><creator>Vollhardt, K. 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Peter C.</au><au>Whitener, Glenn D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Syntheses, Structures, and Reactivity of Radial Oligocyclopentadienyl Metal Complexes: Penta(ferrocenyl)cyclopentadienyl and Congeners</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angewandte Chemie International Edition</addtitle><date>2006-03-06</date><risdate>2006</risdate><volume>45</volume><issue>11</issue><spage>1794</spage><epage>1799</epage><pages>1794-1799</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>“Supra”Cp: Fivefold Negishi coupling of pentaiodocymantrene resulted in radial oligocyclopentadienyl metal complexes (see scheme). These complexes show fascinating conformational and chemical behavior, including MM and CpCp bond formation and the liberation of the novel supraligand penta(ferrocenyl)cyclopentadiene. dba=dibenzylideneacetone.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>16470902</pmid><doi>10.1002/anie.200504047</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2006-03, Vol.45 (11), p.1794-1799 |
| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | carbocations cyclopentadienyl ligands Ferrous Compounds - chemistry metal-metal interactions Metallocenes Metals - chemistry Models, Chemical Molecular Conformation Molecular Probes - chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Organometallic Compounds - pharmacology Oxidation-Reduction palladium radialenes |
| title | Syntheses, Structures, and Reactivity of Radial Oligocyclopentadienyl Metal Complexes: Penta(ferrocenyl)cyclopentadienyl and Congeners |
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