Development of a Sila-Friedel−Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives
An intramolecular sila-Friedel−Crafts reaction was developed and applied to the synthesis of dibenzosilole derivatives. This reaction proceeds under mild conditions to afford the target in relatively high yield, indicating its availability as a versatile synthetic method. The synthesis of trisilasum...
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| Veröffentlicht in: | Journal of the American Chemical Society 2009-10, Vol.131 (40), p.14192-14193 |
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| container_issue | 40 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 131 |
| creator | Furukawa, Shunsuke Kobayashi, Junji Kawashima, Takayuki |
| description | An intramolecular sila-Friedel−Crafts reaction was developed and applied to the synthesis of dibenzosilole derivatives. This reaction proceeds under mild conditions to afford the target in relatively high yield, indicating its availability as a versatile synthetic method. The synthesis of trisilasumanene, a silicon analogue of sumanene, was achieved using the present reaction. |
| doi_str_mv | 10.1021/ja906566r |
| format | Article |
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| ispartof | Journal of the American Chemical Society, 2009-10, Vol.131 (40), p.14192-14193 |
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| language | eng |
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| source | ACS Publications |
| title | Development of a Sila-Friedel−Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives |
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