"Beta-cis-SAr effect" on decarbonylation from alpha,beta-unsaturated acyl and aroyl complexes

"Beta-cis-SAr effect" on decarbonylation from alpha,beta-unsaturated acyl and aroyl complexes

Lone pair of heteroatom located at the beta-cis position in alpha,beta-unsaturated acyl and aroyl group 10 metal complexes dramatically facilitated the stoichiometric and catalytic decarbonylation reactions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-01 (8), p.868-870
Hauptverfasser: Kato, Tomohiro, Kuniyasu, Hitoshi, Kajiura, Takamichi, Minami, Yasunori, Ohtaka, Atsushi, Kinomoto, Masanori, Terao, Jun, Kurosawa, Hideo, Kambe, Nobuaki
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Sprache:eng
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Zusammenfassung:Lone pair of heteroatom located at the beta-cis position in alpha,beta-unsaturated acyl and aroyl group 10 metal complexes dramatically facilitated the stoichiometric and catalytic decarbonylation reactions.
ISSN:1359-7345
1364-548X
DOI:10.1039/b515616e