Synthesis and Reactivity of N-Heterocycle-B(C6F5)3 Complexes. 4. Competition between Pyridine- and Pyrrole-Type Substrates toward B(C6F5)3:  Structure and Dynamics of 7-B(C6F5)3-7-azaindole and [7-Azaindolium]+[HOB(C6F5)3]

Reaction between 7-azaindole and B(C6F5)3 quantitatively yields 7-(C6F5)3B-7-azaindole (4), in which B(C6F5)3 coordinates to the pyridine nitrogen of 7-azaindole, leaving the pyrrole ring unreacted even in the presence of a second equivalent of B(C6F5)3. Reaction of 7-azaindole with H2O−B(C6F5)3 ini...

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Veröffentlicht in:	Inorganic chemistry 2006-02, Vol.45 (4), p.1683-1692
Hauptverfasser:	Focante, Francesca, Camurati, Isabella, Resconi, Luigi, Guidotti, Simona, Beringhelli, Tiziana, D'Alfonso, Giuseppe, Donghi, Daniela, Maggioni, Daniela, Mercandelli, Pierluigi, Sironi, Angelo
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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