Laser-Assisted Synthesis of Au−Ag Alloy Nanoparticles in Solution

By using laser-induced heating, we prepared Au−Ag nanoalloys via three different procedures:  (i) mixture of Au nanoparticles and Ag+ ions irradiated by a 532 nm laser, (ii) mixture of Au and Ag nanoparticles irradiated by a 532 nm laser, and (iii) mixture of Au and Ag nanoparticles irradiated by a...

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Veröffentlicht in:The journal of physical chemistry. B 2006-02, Vol.110 (6), p.2549-2554
Hauptverfasser: Peng, Zhangquan, Spliethoff, Bernd, Tesche, Bernd, Walther, Thomas, Kleinermanns, Karl
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container_end_page 2554
container_issue 6
container_start_page 2549
container_title The journal of physical chemistry. B
container_volume 110
creator Peng, Zhangquan
Spliethoff, Bernd
Tesche, Bernd
Walther, Thomas
Kleinermanns, Karl
description By using laser-induced heating, we prepared Au−Ag nanoalloys via three different procedures:  (i) mixture of Au nanoparticles and Ag+ ions irradiated by a 532 nm laser, (ii) mixture of Au and Ag nanoparticles irradiated by a 532 nm laser, and (iii) mixture of Au and Ag nanoparticles irradiated by a 355 nm laser. Procedure i is advantageous for the production of spherical alloy nanoparticles; in procedures ii and iii, nanoalloys with a sintered structure have been obtained. The morphology of the obtained nanoalloys depends not only on the laser wavelength but also on the concentration of nanoparticles in the initial mixture. When the total concentration of Ag and Au nanoparticles in the mixture is increased, large-scale interlinked networks have been observed upon laser irradiation. It is expected that this selective heating strategy can be extended to prepare other bi- or multi-metallic nanoalloys.
doi_str_mv 10.1021/jp056677w
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subjects Alloys - chemical synthesis
Alloys - chemistry
Alloys - radiation effects
Gold - chemistry
Gold - radiation effects
Lasers
Metal Nanoparticles - chemistry
Metal Nanoparticles - radiation effects
Microscopy, Electron, Transmission - methods
Particle Size
Sensitivity and Specificity
Silver - chemistry
Silver - radiation effects
Solutions - chemistry
title Laser-Assisted Synthesis of Au−Ag Alloy Nanoparticles in Solution
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