Synthesis and characterization of single-phase silicon-substituted α-tricalcium phosphate
Silicon-substituted calcium phosphate (CaP) powders with a Ca/(P+Si) ratio of 1.50 have been prepared by a wet chemical method, with silicon contents up to 2.16 weight percent (wt%). Sintering for 2 h at 1250 °C yields single-phase silicon-substituted alpha tricalcium phosphate (Si- α-TCP) for compo...
Gespeichert in:
| Veröffentlicht in: | Biomaterials 2006-05, Vol.27 (15), p.2916-2925 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2925 |
|---|---|
| container_issue | 15 |
| container_start_page | 2916 |
| container_title | Biomaterials |
| container_volume | 27 |
| creator | Reid, Joel W. Tuck, Loughlin Sayer, Michael Fargo, Karen Hendry, Jason A. |
| description | Silicon-substituted calcium phosphate (CaP) powders with a Ca/(P+Si) ratio of 1.50 have been prepared by a wet chemical method, with silicon contents up to 2.16 weight percent (wt%). Sintering for 2
h at 1250
°C yields single-phase silicon-substituted alpha tricalcium phosphate (Si-
α-TCP) for compositions between 0.59 and 1.14
wt% silicon. The sintered powders have been characterized with X-ray fluorescence (XRF) spectrometry, X-ray diffraction (XRD), attenuated total reflection infrared spectroscopy (ATR-IR) and transmission electron microscopy (TEM). Compositions with less than 0.59
wt% silicon result in mixtures of Si-
α-TCP,
β-TCP, and calcium hydroxyapatite (HA), while compositions with more than 1.14
wt% silicon result in mixtures of Si-
α-TCP and HA. The lattice parameters of single-phase Si-
α-TCP prepared with 0.87
wt% silicon are
a
=
1
2.8
7
4
(
1
)
Å
,
b
=
2
7.3
7
2
(
2
)
Å
,
c
=
1
5.2
2
5
(
1
)
Å
, and
β
=
1
2
6.3
8
(
1
)
°
. |
| doi_str_mv | 10.1016/j.biomaterials.2006.01.007 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_67651877</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0142961206000184</els_id><sourcerecordid>67651877</sourcerecordid><originalsourceid>FETCH-LOGICAL-c440t-2d5b0b3d547b6ba679e3f2f4d684a40831e1b5d35d4bd38c751e51caec7f45df3</originalsourceid><addsrcrecordid>eNqNkc1u1DAQxy1ERbeFV0ARB24J48QfCTdUPqVKHAoXLpY_JqxXSbzYTqXyVn0RngmvdiW4tafRSL__zGh-hLyi0FCg4s2uMT7MOmP0ekpNCyAaoA2AfEI2tJd9zQfgT8kGKGvrQdD2nFyktIPSA2ufkXMqGOvFwDbkx83dkreYfKr04iq71VHbw-TfOvuwVGGskl9-TljvtzphaSZvw1Kn1aTs85rRVX_u6xy91ZP161zttyEVNuNzcjaW-_DFqV6S7x8_fLv6XF9__fTl6t11bRmDXLeOGzCd40waYbSQA3ZjOzIneqYZ9B1FarjruGPGdb2VnCKnVqOVI-Nu7C7J6-PcfQy_VkxZzT5ZnCa9YFiTElLw8hX5INgOdBjgESCVIIXsugK-PYI2hpQijmof_azjnaKgDq7UTv3vSh1cKaCquCrhl6ctq5nR_Yue5BTg_RHA8r1bj1El63Gx6HxEm5UL_jF7_gJYwa9H</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>17076733</pqid></control><display><type>article</type><title>Synthesis and characterization of single-phase silicon-substituted α-tricalcium phosphate</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals Complete</source><creator>Reid, Joel W. ; Tuck, Loughlin ; Sayer, Michael ; Fargo, Karen ; Hendry, Jason A.</creator><creatorcontrib>Reid, Joel W. ; Tuck, Loughlin ; Sayer, Michael ; Fargo, Karen ; Hendry, Jason A.</creatorcontrib><description>Silicon-substituted calcium phosphate (CaP) powders with a Ca/(P+Si) ratio of 1.50 have been prepared by a wet chemical method, with silicon contents up to 2.16 weight percent (wt%). Sintering for 2
h at 1250
°C yields single-phase silicon-substituted alpha tricalcium phosphate (Si-
α-TCP) for compositions between 0.59 and 1.14
wt% silicon. The sintered powders have been characterized with X-ray fluorescence (XRF) spectrometry, X-ray diffraction (XRD), attenuated total reflection infrared spectroscopy (ATR-IR) and transmission electron microscopy (TEM). Compositions with less than 0.59
wt% silicon result in mixtures of Si-
α-TCP,
β-TCP, and calcium hydroxyapatite (HA), while compositions with more than 1.14
wt% silicon result in mixtures of Si-
α-TCP and HA. The lattice parameters of single-phase Si-
α-TCP prepared with 0.87
wt% silicon are
a
=
1
2.8
7
4
(
1
)
Å
,
b
=
2
7.3
7
2
(
2
)
Å
,
c
=
1
5.2
2
5
(
1
)
Å
, and
β
=
1
2
6.3
8
(
1
)
°
.</description><identifier>ISSN: 0142-9612</identifier><identifier>EISSN: 1878-5905</identifier><identifier>DOI: 10.1016/j.biomaterials.2006.01.007</identifier><identifier>PMID: 16448694</identifier><language>eng</language><publisher>Netherlands: Elsevier Ltd</publisher><subject>Bioceramics ; Bone Substitutes - analysis ; Bone Substitutes - chemistry ; Calcium Phosphates - analysis ; Calcium Phosphates - chemistry ; Crystallization - methods ; Hydroxyapatite ; Materials Testing ; Molecular Conformation ; Particle Size ; Phase Transition ; Rietveld refinement ; Silicon ; Silicon - chemistry ; Tricalcium phosphate ; α-TCP</subject><ispartof>Biomaterials, 2006-05, Vol.27 (15), p.2916-2925</ispartof><rights>2006 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c440t-2d5b0b3d547b6ba679e3f2f4d684a40831e1b5d35d4bd38c751e51caec7f45df3</citedby><cites>FETCH-LOGICAL-c440t-2d5b0b3d547b6ba679e3f2f4d684a40831e1b5d35d4bd38c751e51caec7f45df3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0142961206000184$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16448694$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Reid, Joel W.</creatorcontrib><creatorcontrib>Tuck, Loughlin</creatorcontrib><creatorcontrib>Sayer, Michael</creatorcontrib><creatorcontrib>Fargo, Karen</creatorcontrib><creatorcontrib>Hendry, Jason A.</creatorcontrib><title>Synthesis and characterization of single-phase silicon-substituted α-tricalcium phosphate</title><title>Biomaterials</title><addtitle>Biomaterials</addtitle><description>Silicon-substituted calcium phosphate (CaP) powders with a Ca/(P+Si) ratio of 1.50 have been prepared by a wet chemical method, with silicon contents up to 2.16 weight percent (wt%). Sintering for 2
h at 1250
°C yields single-phase silicon-substituted alpha tricalcium phosphate (Si-
α-TCP) for compositions between 0.59 and 1.14
wt% silicon. The sintered powders have been characterized with X-ray fluorescence (XRF) spectrometry, X-ray diffraction (XRD), attenuated total reflection infrared spectroscopy (ATR-IR) and transmission electron microscopy (TEM). Compositions with less than 0.59
wt% silicon result in mixtures of Si-
α-TCP,
β-TCP, and calcium hydroxyapatite (HA), while compositions with more than 1.14
wt% silicon result in mixtures of Si-
α-TCP and HA. The lattice parameters of single-phase Si-
α-TCP prepared with 0.87
wt% silicon are
a
=
1
2.8
7
4
(
1
)
Å
,
b
=
2
7.3
7
2
(
2
)
Å
,
c
=
1
5.2
2
5
(
1
)
Å
, and
β
=
1
2
6.3
8
(
1
)
°
.</description><subject>Bioceramics</subject><subject>Bone Substitutes - analysis</subject><subject>Bone Substitutes - chemistry</subject><subject>Calcium Phosphates - analysis</subject><subject>Calcium Phosphates - chemistry</subject><subject>Crystallization - methods</subject><subject>Hydroxyapatite</subject><subject>Materials Testing</subject><subject>Molecular Conformation</subject><subject>Particle Size</subject><subject>Phase Transition</subject><subject>Rietveld refinement</subject><subject>Silicon</subject><subject>Silicon - chemistry</subject><subject>Tricalcium phosphate</subject><subject>α-TCP</subject><issn>0142-9612</issn><issn>1878-5905</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkc1u1DAQxy1ERbeFV0ARB24J48QfCTdUPqVKHAoXLpY_JqxXSbzYTqXyVn0RngmvdiW4tafRSL__zGh-hLyi0FCg4s2uMT7MOmP0ekpNCyAaoA2AfEI2tJd9zQfgT8kGKGvrQdD2nFyktIPSA2ufkXMqGOvFwDbkx83dkreYfKr04iq71VHbw-TfOvuwVGGskl9-TljvtzphaSZvw1Kn1aTs85rRVX_u6xy91ZP161zttyEVNuNzcjaW-_DFqV6S7x8_fLv6XF9__fTl6t11bRmDXLeOGzCd40waYbSQA3ZjOzIneqYZ9B1FarjruGPGdb2VnCKnVqOVI-Nu7C7J6-PcfQy_VkxZzT5ZnCa9YFiTElLw8hX5INgOdBjgESCVIIXsugK-PYI2hpQijmof_azjnaKgDq7UTv3vSh1cKaCquCrhl6ctq5nR_Yue5BTg_RHA8r1bj1El63Gx6HxEm5UL_jF7_gJYwa9H</recordid><startdate>20060501</startdate><enddate>20060501</enddate><creator>Reid, Joel W.</creator><creator>Tuck, Loughlin</creator><creator>Sayer, Michael</creator><creator>Fargo, Karen</creator><creator>Hendry, Jason A.</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7QP</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope><scope>7QQ</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>F28</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20060501</creationdate><title>Synthesis and characterization of single-phase silicon-substituted α-tricalcium phosphate</title><author>Reid, Joel W. ; Tuck, Loughlin ; Sayer, Michael ; Fargo, Karen ; Hendry, Jason A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c440t-2d5b0b3d547b6ba679e3f2f4d684a40831e1b5d35d4bd38c751e51caec7f45df3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Bioceramics</topic><topic>Bone Substitutes - analysis</topic><topic>Bone Substitutes - chemistry</topic><topic>Calcium Phosphates - analysis</topic><topic>Calcium Phosphates - chemistry</topic><topic>Crystallization - methods</topic><topic>Hydroxyapatite</topic><topic>Materials Testing</topic><topic>Molecular Conformation</topic><topic>Particle Size</topic><topic>Phase Transition</topic><topic>Rietveld refinement</topic><topic>Silicon</topic><topic>Silicon - chemistry</topic><topic>Tricalcium phosphate</topic><topic>α-TCP</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Reid, Joel W.</creatorcontrib><creatorcontrib>Tuck, Loughlin</creatorcontrib><creatorcontrib>Sayer, Michael</creatorcontrib><creatorcontrib>Fargo, Karen</creatorcontrib><creatorcontrib>Hendry, Jason A.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Biomaterials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Reid, Joel W.</au><au>Tuck, Loughlin</au><au>Sayer, Michael</au><au>Fargo, Karen</au><au>Hendry, Jason A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of single-phase silicon-substituted α-tricalcium phosphate</atitle><jtitle>Biomaterials</jtitle><addtitle>Biomaterials</addtitle><date>2006-05-01</date><risdate>2006</risdate><volume>27</volume><issue>15</issue><spage>2916</spage><epage>2925</epage><pages>2916-2925</pages><issn>0142-9612</issn><eissn>1878-5905</eissn><abstract>Silicon-substituted calcium phosphate (CaP) powders with a Ca/(P+Si) ratio of 1.50 have been prepared by a wet chemical method, with silicon contents up to 2.16 weight percent (wt%). Sintering for 2
h at 1250
°C yields single-phase silicon-substituted alpha tricalcium phosphate (Si-
α-TCP) for compositions between 0.59 and 1.14
wt% silicon. The sintered powders have been characterized with X-ray fluorescence (XRF) spectrometry, X-ray diffraction (XRD), attenuated total reflection infrared spectroscopy (ATR-IR) and transmission electron microscopy (TEM). Compositions with less than 0.59
wt% silicon result in mixtures of Si-
α-TCP,
β-TCP, and calcium hydroxyapatite (HA), while compositions with more than 1.14
wt% silicon result in mixtures of Si-
α-TCP and HA. The lattice parameters of single-phase Si-
α-TCP prepared with 0.87
wt% silicon are
a
=
1
2.8
7
4
(
1
)
Å
,
b
=
2
7.3
7
2
(
2
)
Å
,
c
=
1
5.2
2
5
(
1
)
Å
, and
β
=
1
2
6.3
8
(
1
)
°
.</abstract><cop>Netherlands</cop><pub>Elsevier Ltd</pub><pmid>16448694</pmid><doi>10.1016/j.biomaterials.2006.01.007</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0142-9612 |
| ispartof | Biomaterials, 2006-05, Vol.27 (15), p.2916-2925 |
| issn | 0142-9612 1878-5905 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_67651877 |
| source | MEDLINE; Elsevier ScienceDirect Journals Complete |
| subjects | Bioceramics Bone Substitutes - analysis Bone Substitutes - chemistry Calcium Phosphates - analysis Calcium Phosphates - chemistry Crystallization - methods Hydroxyapatite Materials Testing Molecular Conformation Particle Size Phase Transition Rietveld refinement Silicon Silicon - chemistry Tricalcium phosphate α-TCP |
| title | Synthesis and characterization of single-phase silicon-substituted α-tricalcium phosphate |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T04%3A32%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20characterization%20of%20single-phase%20silicon-substituted%20%CE%B1-tricalcium%20phosphate&rft.jtitle=Biomaterials&rft.au=Reid,%20Joel%20W.&rft.date=2006-05-01&rft.volume=27&rft.issue=15&rft.spage=2916&rft.epage=2925&rft.pages=2916-2925&rft.issn=0142-9612&rft.eissn=1878-5905&rft_id=info:doi/10.1016/j.biomaterials.2006.01.007&rft_dat=%3Cproquest_cross%3E67651877%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=17076733&rft_id=info:pmid/16448694&rft_els_id=S0142961206000184&rfr_iscdi=true |