Self-Assembled Nanoreactors as Highly Active Catalysts in the Hydrolytic Kinetic Resolution (HKR) of Epoxides in Water

CoIII(salen) complexes have been immobilized on amphiphilic block copolymers, which self‐assemble in water to give micellar aggregates with a hydrophobic Co(salen) core and a water‐soluble shell (see picture). These aggregates were used to catalyze the hydrolytic kinetic resolution (HKR) of racemic...

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Veröffentlicht in:	Angewandte Chemie International Edition 2006-02, Vol.45 (8), p.1309-1312
Hauptverfasser:	Rossbach, Benjamin M., Leopold, Kerstin, Weberskirch, Ralf
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis epoxides Epoxy Compounds - chemistry Hydrolysis immobilization kinetic resolution Molecular Conformation Molecular Structure Nanotechnology - instrumentation Particle Size polymers self-assembly Water - chemistry
Online-Zugang:	Volltext
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