A Highly Active Palladium Catalyst for Intermolecular Hydroamination. Factors that Control Reactivity and Additions of Functionalized Anilines to Dienes and Vinylarenes

We report a catalyst for intermolecular hydroamination of vinylarenes that is substantially more active for this process than catalysts published previously. With this more reactive catalyst, we demonstrate that additions of amines to vinylarenes and dienes occur in the presence of potentially react...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-02, Vol.128 (6), p.1828-1839
Hauptverfasser:	Johns, Adam M, Utsunomiya, Masaru, Incarvito, Christopher D, Hartwig, John F
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Allyl Compounds - chemistry Amination Aniline Compounds - chemistry Catalysis Chemistry Crystallography, X-Ray Exact sciences and technology Kinetics Kinetics and mechanisms Magnetic Resonance Spectroscopy Organic chemistry Palladium - chemistry Phosphines - chemistry Reactivity and mechanisms Vinyl Compounds - chemistry
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