Boron in the Coordination Spheres of Three Transition-Metal Atoms: Syntheses and Structures of Metalloborylenes Stabilized by a Transition-Metal Base

Boron in the Coordination Spheres of Three Transition-Metal Atoms: Syntheses and Structures of Metalloborylenes Stabilized by a Transition-Metal Base

Naked boron: Reaction of the bromoborylene complex [(η5‐C5Me5)(OC)Fe(μ‐CO)(μ‐BBr)Pt(PCy3)Br] with [M(PCy3)2] (M=Pd, Pt) leads to complexes featuring the unprecedented coordination of one boron atom to three transition‐metal centers (see picture). According to structural and DFT studies, the new comp...

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Veröffentlicht in:Angewandte Chemie International Edition 2006-02, Vol.45 (7), p.1066-1069
Hauptverfasser: Braunschweig, Holger, Radacki, Krzysztof, Rais, Daniela, Seeler, Fabian
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Sprache:eng
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boron
coordination chemistry
density functional calculations
structure elucidation
transition metals
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container_issue 7
container_start_page 1066
container_title Angewandte Chemie International Edition
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creator Braunschweig, Holger
Radacki, Krzysztof
Rais, Daniela
Seeler, Fabian
description Naked boron: Reaction of the bromoborylene complex [(η5‐C5Me5)(OC)Fe(μ‐CO)(μ‐BBr)Pt(PCy3)Br] with [M(PCy3)2] (M=Pd, Pt) leads to complexes featuring the unprecedented coordination of one boron atom to three transition‐metal centers (see picture). According to structural and DFT studies, the new compounds are best described as metalloborylene complexes stabilized by transition‐metal bases.
doi_str_mv 10.1002/anie.200503807
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subjects boron
coordination chemistry
density functional calculations
structure elucidation
transition metals
title Boron in the Coordination Spheres of Three Transition-Metal Atoms: Syntheses and Structures of Metalloborylenes Stabilized by a Transition-Metal Base
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