Excited-State Hydrogen-Atom Transfer along Solvent Wires:  Water Molecules Stop the Transfer

Excited-state hydrogen-atom transfer (ESHAT) along a hydrogen-bonded solvent wire occurs for the supersonically cooled n = 3 ammonia-wire cluster attached to the scaffold molecule 7-hydroxyquinoline (7HQ) [Tanner, C.; et al. Science 2003, 302, 1736]. Here, we study the analogous three-membered solve...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2006-02, Vol.110 (5), p.1758-1766
Hauptverfasser: Tanner, Christian, Thut, Markus, Steinlin, Andreas, Manca, Carine, Leutwyler, Samuel
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Sprache:eng
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