Picosecond X-ray Absorption Spectroscopy of a Photoinduced Iron(II) Spin Crossover Reaction in Solution

In this study, we perform steady-state and time-resolved X-ray absorption spectroscopy (XAS) on the iron K-edge of [Fe(tren(py)3)](PF6)2 dissolved in acetonitrile solution. Static XAS measurements on the low-spin parent compound and its high-spin analogue, [Fe(tren(6-Me-py)3)](PF6)2, reveal distinct...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2006-01, Vol.110 (1), p.38-44
Hauptverfasser:	Khalil, Munira, Marcus, Matthew A, Smeigh, Amanda L, McCusker, James K, Chong, Henry H. W, Schoenlein, Robert W
Format:	Artikel
Sprache:	eng
Schlagworte:	Ferrous Compounds - chemistry Photochemistry Sensitivity and Specificity Solutions - chemistry Spectrum Analysis - instrumentation Spectrum Analysis - methods Time Factors X-Rays
Online-Zugang:	Volltext
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