Vacuum Thermal Degradation of Poly(ethylene oxide)

Thermal degradation of poly(ethylene oxide) (PEO) was studied under vacuum conditions. PEO macromolecules degrade predominantly by random chain scission of a backbone with elimination of oligomer fragments. The reactions include the mechanism of radical termination by disproportionation. The elimina...

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Veröffentlicht in:	The journal of physical chemistry. B 2009-03, Vol.113 (10), p.2984-2989
Hauptverfasser:	Choukourov, Andrei, Grinevich, Andrey, Polonskyi, Oleksandr, Hanus, Jan, Kousal, Jaroslav, Slavinska, Danka, Biederman, Hynek
Format:	Artikel
Sprache:	eng
Schlagworte:	B: Macromolecules, Soft Matter Biocompatible Materials - chemistry Carbon - chemistry Equipment Design Hot Temperature Hydrogen - chemistry Mass Spectrometry - methods Materials Testing Models, Chemical Molecular Weight Polyethylene Glycols - chemistry Spectroscopy, Fourier Transform Infrared Surface Properties Temperature Vacuum Water - chemistry
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