Preconcentration and separation of trace amount of copper (II) on N1, N2-bis( 4-fluorobenzylidene )ethane-1,2-diamine loaded on Sepabeads SP70
A sensitive and simple method for the preconcentration of copper (II) ions has been reported. The method is based on the adsorption of copper ion N(1), N(2)-bis(4-fluorobenzylidene)ethane-1,2-diamine loaded on Sepabeads. The sorpted copper content was eluted by 8 ml of 4M nitric acid in acetone. The...
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Veröffentlicht in: | Journal of hazardous materials 2009-10, Vol.170 (1), p.169-174 |
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creator | GHAEDI, M SHABANI, R SHOKROLLAHI, A MONTAZEROZOHORI, M SAHRAIEAN, A SOYLAK, M |
description | A sensitive and simple method for the preconcentration of copper (II) ions has been reported. The method is based on the adsorption of copper ion N(1), N(2)-bis(4-fluorobenzylidene)ethane-1,2-diamine loaded on Sepabeads. The sorpted copper content was eluted by 8 ml of 4M nitric acid in acetone. The influences of the analytical parameters including pH and sample volume were investigated. The interference effects of matrix ions on the retentions of the copper (II) ions were also examined. The recovery of understudy analyte was generally higher than 95%. The method has been successfully applied to the evaluation of copper contents in some real samples including water samples, vegetable samples and milk samples. |
doi_str_mv | 10.1016/j.jhazmat.2009.04.110 |
format | Article |
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The method is based on the adsorption of copper ion N(1), N(2)-bis(4-fluorobenzylidene)ethane-1,2-diamine loaded on Sepabeads. The sorpted copper content was eluted by 8 ml of 4M nitric acid in acetone. The influences of the analytical parameters including pH and sample volume were investigated. The interference effects of matrix ions on the retentions of the copper (II) ions were also examined. The recovery of understudy analyte was generally higher than 95%. The method has been successfully applied to the evaluation of copper contents in some real samples including water samples, vegetable samples and milk samples.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2009.04.110</identifier><identifier>PMID: 19481865</identifier><identifier>CODEN: JHMAD9</identifier><language>eng</language><publisher>Kidlington: Elsevier</publisher><subject>Adsorption ; Animals ; Applied sciences ; Chemical engineering ; Copper - isolation & purification ; Diamines - chemistry ; Exact sciences and technology ; Food Analysis - methods ; Hydrogen-Ion Concentration ; Ions ; Microspheres ; Milk - chemistry ; Pollution ; Trace Elements - isolation & purification ; Vegetables - chemistry ; Water - chemistry</subject><ispartof>Journal of hazardous materials, 2009-10, Vol.170 (1), p.169-174</ispartof><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1825-f02b648946517d78ea01ddc4bce79eea48a452720914cb10adfaae04d7c1765b3</citedby><cites>FETCH-LOGICAL-c1825-f02b648946517d78ea01ddc4bce79eea48a452720914cb10adfaae04d7c1765b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21838920$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19481865$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>GHAEDI, M</creatorcontrib><creatorcontrib>SHABANI, R</creatorcontrib><creatorcontrib>SHOKROLLAHI, A</creatorcontrib><creatorcontrib>MONTAZEROZOHORI, M</creatorcontrib><creatorcontrib>SAHRAIEAN, A</creatorcontrib><creatorcontrib>SOYLAK, M</creatorcontrib><title>Preconcentration and separation of trace amount of copper (II) on N1, N2-bis( 4-fluorobenzylidene )ethane-1,2-diamine loaded on Sepabeads SP70</title><title>Journal of hazardous materials</title><addtitle>J Hazard Mater</addtitle><description>A sensitive and simple method for the preconcentration of copper (II) ions has been reported. The method is based on the adsorption of copper ion N(1), N(2)-bis(4-fluorobenzylidene)ethane-1,2-diamine loaded on Sepabeads. The sorpted copper content was eluted by 8 ml of 4M nitric acid in acetone. The influences of the analytical parameters including pH and sample volume were investigated. The interference effects of matrix ions on the retentions of the copper (II) ions were also examined. The recovery of understudy analyte was generally higher than 95%. The method has been successfully applied to the evaluation of copper contents in some real samples including water samples, vegetable samples and milk samples.</description><subject>Adsorption</subject><subject>Animals</subject><subject>Applied sciences</subject><subject>Chemical engineering</subject><subject>Copper - isolation & purification</subject><subject>Diamines - chemistry</subject><subject>Exact sciences and technology</subject><subject>Food Analysis - methods</subject><subject>Hydrogen-Ion Concentration</subject><subject>Ions</subject><subject>Microspheres</subject><subject>Milk - chemistry</subject><subject>Pollution</subject><subject>Trace Elements - isolation & purification</subject><subject>Vegetables - chemistry</subject><subject>Water - chemistry</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpFkcFu1DAQhi0EotvCI4B8AbVSEzyOEyfHqqKwUlUqFc7WxJ6oWSVxsJND-xA8M141gpM19vd7xv4Y-wAiBwHVl0N-eMTnEZdcCtHkQuUA4hXbQa2LrCiK6jXbiUKorKgbdcJOYzwIIUCX6i07gUbVUFfljv25D2T9ZGlaAi69nzhOjkeacSt9x9OJJY6jX6flWFs_zxT4-X5_wRNxB5f8TmZtH8-5yrph9cG3ND0_Db2jifgFLY84UQaXMnM9jn3aGzw6csf0Q2rVErrIH-61eMfedDhEer-tZ-zXzdef19-z2x_f9tdXt5mFWpZZJ2RbqfSwqgTtdE0owDmrWku6IUJVoyqllqIBZVsQ6DpEEsppC7oq2-KMfX65dw7-90pxMWMfLQ1DGtSv0VS6lKXSkMDyBbTBxxioM3PoRwxPBoQ5ijAHs4kwRxFGKJNEpNzHrcHajuT-p7afT8CnDcBocegCTraP_zgJdRInRfEXBvWS2Q</recordid><startdate>20091015</startdate><enddate>20091015</enddate><creator>GHAEDI, M</creator><creator>SHABANI, R</creator><creator>SHOKROLLAHI, A</creator><creator>MONTAZEROZOHORI, M</creator><creator>SAHRAIEAN, A</creator><creator>SOYLAK, M</creator><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20091015</creationdate><title>Preconcentration and separation of trace amount of copper (II) on N1, N2-bis( 4-fluorobenzylidene )ethane-1,2-diamine loaded on Sepabeads SP70</title><author>GHAEDI, M ; SHABANI, R ; SHOKROLLAHI, A ; MONTAZEROZOHORI, M ; SAHRAIEAN, A ; SOYLAK, M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1825-f02b648946517d78ea01ddc4bce79eea48a452720914cb10adfaae04d7c1765b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Adsorption</topic><topic>Animals</topic><topic>Applied sciences</topic><topic>Chemical engineering</topic><topic>Copper - isolation & purification</topic><topic>Diamines - chemistry</topic><topic>Exact sciences and technology</topic><topic>Food Analysis - methods</topic><topic>Hydrogen-Ion Concentration</topic><topic>Ions</topic><topic>Microspheres</topic><topic>Milk - chemistry</topic><topic>Pollution</topic><topic>Trace Elements - isolation & purification</topic><topic>Vegetables - chemistry</topic><topic>Water - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>GHAEDI, M</creatorcontrib><creatorcontrib>SHABANI, R</creatorcontrib><creatorcontrib>SHOKROLLAHI, A</creatorcontrib><creatorcontrib>MONTAZEROZOHORI, M</creatorcontrib><creatorcontrib>SAHRAIEAN, A</creatorcontrib><creatorcontrib>SOYLAK, M</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>GHAEDI, M</au><au>SHABANI, R</au><au>SHOKROLLAHI, A</au><au>MONTAZEROZOHORI, M</au><au>SAHRAIEAN, A</au><au>SOYLAK, M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preconcentration and separation of trace amount of copper (II) on N1, N2-bis( 4-fluorobenzylidene )ethane-1,2-diamine loaded on Sepabeads SP70</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2009-10-15</date><risdate>2009</risdate><volume>170</volume><issue>1</issue><spage>169</spage><epage>174</epage><pages>169-174</pages><issn>0304-3894</issn><eissn>1873-3336</eissn><coden>JHMAD9</coden><abstract>A sensitive and simple method for the preconcentration of copper (II) ions has been reported. The method is based on the adsorption of copper ion N(1), N(2)-bis(4-fluorobenzylidene)ethane-1,2-diamine loaded on Sepabeads. The sorpted copper content was eluted by 8 ml of 4M nitric acid in acetone. The influences of the analytical parameters including pH and sample volume were investigated. The interference effects of matrix ions on the retentions of the copper (II) ions were also examined. The recovery of understudy analyte was generally higher than 95%. The method has been successfully applied to the evaluation of copper contents in some real samples including water samples, vegetable samples and milk samples.</abstract><cop>Kidlington</cop><pub>Elsevier</pub><pmid>19481865</pmid><doi>10.1016/j.jhazmat.2009.04.110</doi><tpages>6</tpages></addata></record> |
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subjects | Adsorption Animals Applied sciences Chemical engineering Copper - isolation & purification Diamines - chemistry Exact sciences and technology Food Analysis - methods Hydrogen-Ion Concentration Ions Microspheres Milk - chemistry Pollution Trace Elements - isolation & purification Vegetables - chemistry Water - chemistry |
title | Preconcentration and separation of trace amount of copper (II) on N1, N2-bis( 4-fluorobenzylidene )ethane-1,2-diamine loaded on Sepabeads SP70 |
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