Preconcentration and separation of trace amount of copper (II) on N1, N2-bis( 4-fluorobenzylidene )ethane-1,2-diamine loaded on Sepabeads SP70

A sensitive and simple method for the preconcentration of copper (II) ions has been reported. The method is based on the adsorption of copper ion N(1), N(2)-bis(4-fluorobenzylidene)ethane-1,2-diamine loaded on Sepabeads. The sorpted copper content was eluted by 8 ml of 4M nitric acid in acetone. The...

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Veröffentlicht in:Journal of hazardous materials 2009-10, Vol.170 (1), p.169-174
Hauptverfasser: GHAEDI, M, SHABANI, R, SHOKROLLAHI, A, MONTAZEROZOHORI, M, SAHRAIEAN, A, SOYLAK, M
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container_issue 1
container_start_page 169
container_title Journal of hazardous materials
container_volume 170
creator GHAEDI, M
SHABANI, R
SHOKROLLAHI, A
MONTAZEROZOHORI, M
SAHRAIEAN, A
SOYLAK, M
description A sensitive and simple method for the preconcentration of copper (II) ions has been reported. The method is based on the adsorption of copper ion N(1), N(2)-bis(4-fluorobenzylidene)ethane-1,2-diamine loaded on Sepabeads. The sorpted copper content was eluted by 8 ml of 4M nitric acid in acetone. The influences of the analytical parameters including pH and sample volume were investigated. The interference effects of matrix ions on the retentions of the copper (II) ions were also examined. The recovery of understudy analyte was generally higher than 95%. The method has been successfully applied to the evaluation of copper contents in some real samples including water samples, vegetable samples and milk samples.
doi_str_mv 10.1016/j.jhazmat.2009.04.110
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source MEDLINE; Elsevier ScienceDirect Journals
subjects Adsorption
Animals
Applied sciences
Chemical engineering
Copper - isolation & purification
Diamines - chemistry
Exact sciences and technology
Food Analysis - methods
Hydrogen-Ion Concentration
Ions
Microspheres
Milk - chemistry
Pollution
Trace Elements - isolation & purification
Vegetables - chemistry
Water - chemistry
title Preconcentration and separation of trace amount of copper (II) on N1, N2-bis( 4-fluorobenzylidene )ethane-1,2-diamine loaded on Sepabeads SP70
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