Metal Ion Catalysis of Natural Products Transformations. Novel Aldopentose Disproportionation Reactions Catalyzed by Rhodium(III)

The detailed stoichiometry of the reaction between the aldopentoses, ribose, arabinose, lyxose, and xylose, and the cis rhodium(III) complex of the macrocyclic tetraamine ligand rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane in weakly acidic aqueous solution has been studied by 13C...

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Veröffentlicht in:	Inorganic chemistry 2005-03, Vol.44 (6), p.1950-1954
Hauptverfasser:	Mønsted, L, Mønsted, O
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological Products - metabolism Carbon Isotopes Catalysis Chromium - chemistry Hydrogen-Ion Concentration Molecular Structure Nuclear Magnetic Resonance, Biomolecular Pentoses - chemistry Rhodium - chemistry Water - chemistry
Online-Zugang:	Volltext
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