Preparation and crystallographic characterization of C60Cl24

C60Cl24 has been synthesized by the chlorination of C60 with VCl4 or C60Br24 with SbCl5; the X-ray single crystal structure of C60Cl24.2Br2 confirmed the molecular T(h) symmetry in good agreement with the IR data and theoretical calculations.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-01 (11), p.1411-1413
Hauptverfasser: Shustova, Natalia B, Popov, Alexey A, Sidorov, Lev N, Turnbull, Andrew P, Kemnitz, Erhard, Troyanov, Sergey I
Format: Artikel
Sprache:eng
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Zusammenfassung:C60Cl24 has been synthesized by the chlorination of C60 with VCl4 or C60Br24 with SbCl5; the X-ray single crystal structure of C60Cl24.2Br2 confirmed the molecular T(h) symmetry in good agreement with the IR data and theoretical calculations.
ISSN:1359-7345
1364-548X
DOI:10.1039/b416341a