Practical Synthesis of Enantiopure Spiro[4.4]nonane C-(2‘-Deoxy)ribonucleosides

The levorotatory diol 7 has been sequentially monosilylated, dehydrated, and oxidized at the allylic methylene group to provide (+)-12. The enantiomeric dextrorotatory diol 7 has been directed down a different sequence of steps involving monosilylation, dehydration, hydroboration, Swern oxidation, a...

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Veröffentlicht in:	Journal of organic chemistry 2005-03, Vol.70 (5), p.1597-1604
Hauptverfasser:	Hartung, Ryan, Paquette, Leo A
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes - chemistry Carbohydrates. Nucleosides and nucleotides Chemistry Deoxyribonucleosides - chemical synthesis Exact sciences and technology Molecular Conformation Nucleosides, nucleotides and oligonucleotides Organic chemistry Preparations and properties Spiro Compounds - chemistry Stereoisomerism
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