Low-Molecular-Weight Poly(α-methyl β,L-malate) of Microbial Origin: Synthesis and Crystallization
Low‐molecular‐weight poly(α‐methyl β,L‐malate) made of approximately 25–30 units was prepared from microbial poly(β,L‐malic acid) by treatment with diazomethane. The thermal characterization of the polymalate methyl ester was carried out and its crystalline structure was preliminary examined. Its ab...
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| Veröffentlicht in: | Macromolecular bioscience 2005-02, Vol.5 (2), p.172-176 |
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| container_title | Macromolecular bioscience |
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| creator | Fernández, Carlos E. Mancera, Manuel Holler, Eggehard Bou, Jordi J. Galbis, Juan A. Muñoz-Guerra, Sebastián |
| description | Low‐molecular‐weight poly(α‐methyl β,L‐malate) made of approximately 25–30 units was prepared from microbial poly(β,L‐malic acid) by treatment with diazomethane. The thermal characterization of the polymalate methyl ester was carried out and its crystalline structure was preliminary examined. Its ability to crystallize both from solution and from the melt was comparatively evaluated.
Poly(α‐methyl β,L‐malate) spherulitic film cast from CHCl3. |
| doi_str_mv | 10.1002/mabi.200400166 |
| format | Article |
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Biosci</addtitle><date>2005-02-23</date><risdate>2005</risdate><volume>5</volume><issue>2</issue><spage>172</spage><epage>176</epage><pages>172-176</pages><issn>1616-5187</issn><eissn>1616-5195</eissn><abstract>Low‐molecular‐weight poly(α‐methyl β,L‐malate) made of approximately 25–30 units was prepared from microbial poly(β,L‐malic acid) by treatment with diazomethane. The thermal characterization of the polymalate methyl ester was carried out and its crystalline structure was preliminary examined. Its ability to crystallize both from solution and from the melt was comparatively evaluated.
Poly(α‐methyl β,L‐malate) spherulitic film cast from CHCl3.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>15719432</pmid><doi>10.1002/mabi.200400166</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Macromolecular bioscience, 2005-02, Vol.5 (2), p.172-176 |
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| language | eng |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Animals biopolymers Crystallization Diazomethane - chemistry Magnetic Resonance Spectroscopy Malates - chemical synthesis Malates - chemistry Malates - isolation & purification Malates - metabolism Physarum polycephalum - metabolism Polymers - chemical synthesis Polymers - chemistry Polymers - isolation & purification Polymers - metabolism synthesis X-Ray Diffraction |
| title | Low-Molecular-Weight Poly(α-methyl β,L-malate) of Microbial Origin: Synthesis and Crystallization |
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