Design and Study of PhosphocavitandsA New Family of Cavity Systems
The design of phosphorus-containing cavity architectures that are of interest for biomimetics and other interdisciplinary sciences is among the most high-priority lines of research in modern organophosphorus chemistry. This Account acquaints the readers with methods for the design of rigid phosphoma...
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| Veröffentlicht in: | Accounts of chemical research 2005-02, Vol.38 (2), p.108-116 |
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| container_title | Accounts of chemical research |
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| creator | Nifantyev, Eduard E Maslennikova, Vera I Merkulov, Roman V |
| description | The design of phosphorus-containing cavity architectures that are of interest for biomimetics and other interdisciplinary sciences is among the most high-priority lines of research in modern organophosphorus chemistry. This Account acquaints the readers with methods for the design of rigid phosphomacrocyclic systems based on resorcinarenes, which differ in the nature of the phosphorus functions on the upper rim of the molecular bowl and have fixed dimensions of the molecular cavity. The authors demonstrate the possibility of attaining stereoselectivity in the synthesis of phospho(III)cavitands and their various transformations. |
| doi_str_mv | 10.1021/ar0401810 |
| format | Article |
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The authors demonstrate the possibility of attaining stereoselectivity in the synthesis of phospho(III)cavitands and their various transformations.</description><subject>Calixarenes</subject><subject>Cyclization</subject><subject>Ethers, Cyclic - chemical synthesis</subject><subject>Ethers, Cyclic - chemistry</subject><subject>Molecular Structure</subject><subject>Organophosphorus Compounds - chemical synthesis</subject><subject>Organophosphorus Compounds - chemistry</subject><subject>Phenylalanine - analogs & derivatives</subject><subject>Phenylalanine - chemistry</subject><subject>Phosphorylation</subject><subject>Resorcinols - chemical synthesis</subject><subject>Resorcinols - chemistry</subject><issn>0001-4842</issn><issn>1520-4898</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9kc1OwkAUhSdGI4gufAHTje6qdzqdvyVBUBOiEDAxbibTdpBiS7HTqn0SX8Wn8hkcBFnde3O-nNyTg9AphksMAb7SJYSABYY91MY0AD8UUuyjNgBgt4dBCx1Zu3BnEDJ-iFqYcpCcQBv1r41NX5aeXibepKqTxitm3mhe2NW8iPV7WjnB_nx9d7178-ENdJ5mf0hvrTXepLGVye0xOpjpzJqT7eygx0F_2rv1hw83d73u0NcB55U_w1S6PwWQCIPAjOlEE81izZMgkoIFggouCGZAJYtwQgFklAidMBkbSSjpoIuN76os3mpjK5WnNjZZppemqK1iPCRAgTjwbAvWUW4StSrTXJeN-g_uAH8DpC7A507X5aszIZyq6WiietPx05jJkXp2_PmG17FVi6Iuly6nwqDWBahdAeQXNBxzNA</recordid><startdate>20050201</startdate><enddate>20050201</enddate><creator>Nifantyev, Eduard E</creator><creator>Maslennikova, Vera I</creator><creator>Merkulov, Roman V</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20050201</creationdate><title>Design and Study of PhosphocavitandsA New Family of Cavity Systems</title><author>Nifantyev, Eduard E ; Maslennikova, Vera I ; Merkulov, Roman V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a277t-f159018803b108166ada3a6ca7d2b9862858783160596b1d5009bd8ad69ce9353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Calixarenes</topic><topic>Cyclization</topic><topic>Ethers, Cyclic - chemical synthesis</topic><topic>Ethers, Cyclic - chemistry</topic><topic>Molecular Structure</topic><topic>Organophosphorus Compounds - chemical synthesis</topic><topic>Organophosphorus Compounds - chemistry</topic><topic>Phenylalanine - analogs & derivatives</topic><topic>Phenylalanine - chemistry</topic><topic>Phosphorylation</topic><topic>Resorcinols - chemical synthesis</topic><topic>Resorcinols - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nifantyev, Eduard E</creatorcontrib><creatorcontrib>Maslennikova, Vera I</creatorcontrib><creatorcontrib>Merkulov, Roman V</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Accounts of chemical research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nifantyev, Eduard E</au><au>Maslennikova, Vera I</au><au>Merkulov, Roman V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design and Study of PhosphocavitandsA New Family of Cavity Systems</atitle><jtitle>Accounts of chemical research</jtitle><addtitle>Acc. 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| ispartof | Accounts of chemical research, 2005-02, Vol.38 (2), p.108-116 |
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| source | ACS Publications; MEDLINE |
| subjects | Calixarenes Cyclization Ethers, Cyclic - chemical synthesis Ethers, Cyclic - chemistry Molecular Structure Organophosphorus Compounds - chemical synthesis Organophosphorus Compounds - chemistry Phenylalanine - analogs & derivatives Phenylalanine - chemistry Phosphorylation Resorcinols - chemical synthesis Resorcinols - chemistry |
| title | Design and Study of PhosphocavitandsA New Family of Cavity Systems |
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