Carbohydrate-Metal Interactions Shaped by Supramolecular Assembling

Cyclodextrin ligands: Carbohydrates can be used as framework molecules that provide patterns of metal‐binding oxygen atoms. The divalent forms of the biologically important metals iron and manganese can be part of such assemblies (see structure: Fe blue, O red, counterion green, hydrogen bonds betwe...

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Veröffentlicht in:Angewandte Chemie International Edition 2005-01, Vol.44 (6), p.924-927
Hauptverfasser: Geißelmann, Andreas, Klüfers, Peter, Kropfgans, Claudia, Mayer, Peter, Piotrowski, Holger
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container_issue 6
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container_title Angewandte Chemie International Edition
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creator Geißelmann, Andreas
Klüfers, Peter
Kropfgans, Claudia
Mayer, Peter
Piotrowski, Holger
description Cyclodextrin ligands: Carbohydrates can be used as framework molecules that provide patterns of metal‐binding oxygen atoms. The divalent forms of the biologically important metals iron and manganese can be part of such assemblies (see structure: Fe blue, O red, counterion green, hydrogen bonds between water molecules yellow). The assemblies are stabilized by favorable contributions other than the carbohydrate–metal interaction.
doi_str_mv 10.1002/anie.200460079
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subjects bismuth
Carbohydrates - chemistry
Crystallography, X-Ray
cyclodextrins
Hydrogen Bonding
iron
manganese
Metals - chemistry
Molecular Structure
vanadium
title Carbohydrate-Metal Interactions Shaped by Supramolecular Assembling
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