Aggregation-Induced Dissociation of HCl(H₂O)₄ Below 1 K: The Smallest Droplet of Acid

Acid dissociation and the subsequent solvation of the charged fragments at ultracold temperatures in nanoenvironments, as distinct from ambient bulk water, are relevant to atmospheric and interstellar chemistry but remain poorly understood. Here we report the experimental observation of a nanoscopic...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2009-06, Vol.324 (5934), p.1545-1548
Hauptverfasser:	Gutberlet, Anna, Schwaab, Gerhard, Birer, Özgür, Masia, Marco, Kaczmarek, Anna, Forbert, Harald, Havenith, Martina, Marx, Dominik
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra Acids Aggregation Astronomy Atoms Chemical reactions Cooling Dissolution Earth, ocean, space Exact sciences and technology Fundamental aspects of astrophysics Fundamental astronomy and astrophysics. Instrumentation, techniques, and astronomical observations Helium Infrared radiation Ions Mass spectroscopy Molecular and chemical processes and interactions Molecules Organic Chemistry Protons Solvation Spectrum analysis Water
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