Wavelength-Dependent Electron and Energy Transfer Pathways in a Side-to-Face Ruthenium Porphyrin/Perylene Bisimide Assembly

A new side-to-face supramolecular array of chromophores, where a pyridyl-substituted perylene bisimide dye axially binds to two ruthenium porphyrin fragments, has been prepared by self-assembly. The array is formulated as DPyPBI[Ru(TPP)(CO)]2, where DPyPBI = N,N‘-di(4-pyridyl)-1,6,7,12-tetra(4-tert-...

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Veröffentlicht in:Journal of the American Chemical Society 2005-02, Vol.127 (5), p.1454-1462
Hauptverfasser: Prodi, Anna, Chiorboli, Claudio, Scandola, Franco, Iengo, Elisabetta, Alessio, Enzo, Dobrawa, Rainer, Würthner, Frank
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Sprache:eng
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