X-ray Absorption Fine Structure Study of the Effect of Protonation on Disorder and Multiple Scattering in Phosphate Solutions and Solids

Phosphorus K-edge X-ray absorption fine structure (XAFS) was explored as a means to distinguish between aqueous and solid phosphates and to detect changes in phosphate protonation state. Data were collected for H3PO4, KH2PO4, K2HPO4 and K3PO4 solids and solutions and for the more complex phosphates,...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2009-06, Vol.113 (25), p.6895-6903
Hauptverfasser:	Rouff, Ashaki A, Rabe, Stefan, Nachtegaal, Maarten, Vogel, Frédéric
Format:	Artikel
Sprache:	eng
Schlagworte:	A: Kinetics, Spectroscopy Phosphates - chemistry Protons Solutions Spectrometry, X-Ray Emission
Online-Zugang:	Volltext
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