Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters Using Molecular Oxygen as Stoichiometric Oxidant

A vanadium-catalyzed method for the oxidative kinetic resolution of α-hydroxyesters, using oxygen as the terminal oxidant, is described. The catalyst is generated in situ from vanadium(V) tri-iso-propoxyoxide in combination with a tridentate ligand derived from 3,5-di-tert-butylsalicylaldehyde and (...

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Veröffentlicht in:	Journal of the American Chemical Society 2005-02, Vol.127 (4), p.1090-1091
Hauptverfasser:	Radosevich, Alexander T, Musich, Christine, Toste, F. Dean
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactivity Chemistry Exact sciences and technology Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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