Bonding in HNO-Myoglobin as Characterized by X-ray Absorption and Resonance Raman Spectroscopies

The EXAFS and resonance Raman spectra on the HNO-myoglobin adduct, 1, are consistent with the presence of HNO bound to a heme center. The three-dimensional structure about the heme center of 1 obtained from multiple-scattering (MS) analysis of the EXAFS of the heme protein yielded an Fe−N−O bond ang...

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Veröffentlicht in:Journal of the American Chemical Society 2005-01, Vol.127 (3), p.814-815
Hauptverfasser: Immoos, Chad E, Sulc, Filip, Farmer, Patrick J, Czarnecki, Kazimierz, Bocian, David F, Levina, Aviva, Aitken, Jade B, Armstrong, Robert S, Lay, Peter A
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Sprache:eng
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