Local and Collective Motions in Precise Polyolefins with Alkyl Branches: A Combination of ²H and ¹³C Solid-State NMR Spectroscopy

Branching out: The mobility of linear polymers changes upon branching, which has a pronounced effect on processability and drawability. Regularly branched model polyolefins were studied by advanced solid-state NMR spectroscopy, and twist defects around the branches in the crystalline regions are ide...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie (International ed.) 2009, Vol.48 (25), p.4617-4620
Hauptverfasser:	Wei, Yuying, Graf, Robert, Sworen, John C, Cheng, Chi-Yuan, Bowers, Clifford R, Wagener, Kenneth B, Spiess, Hans Wolfgang
Format:	Artikel
Sprache:	eng
Schlagworte:	defects molecular dynamics NMR spectroscopy polymer branching polyolefins
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!