Organosoluble Copper Clusters as Precatalysts for Carbon−Heteroelement Bond-Forming Reactions:  Microwave and Conventional Heating

Organosoluble Copper Clusters as Precatalysts for Carbon−Heteroelement Bond-Forming Reactions:  Microwave and Conventional Heating

The coupling of aryl iodides with alcohols under mild conditions has been explored using self-assembled octanuclear copper clusters as catalysts. Reactions involving tetrahydrofurfuryl alcohol were typically complete in 4−8 h at 110 °C using an oil bath or 1−3 h with microwave heating. High yields o...

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Veröffentlicht in:Journal of organic chemistry 2005-01, Vol.70 (1), p.244-250
Hauptverfasser: Manbeck, Gerald F, Lipman, Adam J, Stockland, Robert A, Freidl, Adrienne L, Hasler, Amy F, Stone, Joshua J, Guzei, Ilia A
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Organic chemistry
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container_end_page 250
container_issue 1
container_start_page 244
container_title Journal of organic chemistry
container_volume 70
creator Manbeck, Gerald F
Lipman, Adam J
Stockland, Robert A
Freidl, Adrienne L
Hasler, Amy F
Stone, Joshua J
Guzei, Ilia A
description The coupling of aryl iodides with alcohols under mild conditions has been explored using self-assembled octanuclear copper clusters as catalysts. Reactions involving tetrahydrofurfuryl alcohol were typically complete in 4−8 h at 110 °C using an oil bath or 1−3 h with microwave heating. High yields of alkyl aryl ethers were obtained with catalyst loadings as low as 0.4 mol % cluster.
doi_str_mv 10.1021/jo048761y
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Organic chemistry
title Organosoluble Copper Clusters as Precatalysts for Carbon−Heteroelement Bond-Forming Reactions:  Microwave and Conventional Heating
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