Photoinduced charge transfer reaction at surfaces. III. (HF)2...Na n/LiF(001)+hnu(640 nm)-->HFF-Na n +/LiF(001)+H(g)

A sub-monolayer of atomic sodium was deposited on a LiF(001) surface at 40 K. The adsorbed sodium exists at the surface as single atoms and clusters. The surface was dosed with 1 L of HF, to form adsorbed (HF)2...Na(n) (n=1,2,3,...) complexes, which were then irradiated by 640 nm laser light, to ind...

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Veröffentlicht in:	The Journal of chemical physics 2005-01, Vol.122 (1), p.14705-14705
Hauptverfasser:	Dobrin, Sergey, Giorgi, Javier B, Naumkin, Fedor Y, Polanyi, John C
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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