An Intramolecular Organocatalytic Cyclopropanation Reaction

Nucleophilic tertiary amines catalyze an intramolecular cyclopropanation reaction to give [n.1.0]bicycloalkanes in good yield (see scheme). The reaction is tolerant of a wide range of functional groups and is highly diastereoselective. Furthermore, when a catalytic amount of a chiral cinchona alkalo...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2004-05, Vol.43 (20), p.2681-2684
Hauptverfasser:	Bremeyer, Nadine, Smith, Stephen C., Ley, Steven V., Gaunt, Matthew J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Cyclization cyclopropanation Cyclopropanes - chemistry diastereoselectivity enantioselectivity homogeneous catalysis Models, Chemical Molecular Structure Stereoisomerism
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!