Alkylation of a Dimolybdenum SO Bridge, Subsequent Reactions, and Characterization of the Thioperoxide Bridge

The SO bridge of the complex, [Mo2(NTo)2(S2P(OEt)2)2(μ-O2CMe)(μ-SBn)(μ-SO)], 1, displayed nucleophilicity at O, giving alkylation products [Mo2(NTo)2(S2P(OEt)2)2(μ-O2CMe)(μ-SBn)(μ-SOR)]+, 4 + , which contained the thioperoxide bridge. These cations were then subject to nucleophilic attack by two pat...

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Veröffentlicht in:	Inorganic chemistry 2009-06, Vol.48 (11), p.5027-5038
Hauptverfasser:	Minh Tuong, Chi, Hammons, Whitney K, Howarth, Ashley L, Lutz, Kelly E, Maduvu, Ackim D, Haysley, Laura B, Allred, Brian R. T, Hoyt, Lenore K, Mashuta, Mark S, Noble, Mark E
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkylation Crystallography, X-Ray Ligands Models, Molecular Molecular Conformation Molybdenum - chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxygen - chemistry Peroxides - chemistry Stereoisomerism Sulfur - chemistry
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