Influence of the atomic structure on the Raman spectra of graphite edges
A study of step edges in graphite with different atomic structures combining Raman spectroscopy and scanning probe microscopy is presented. The orientation of the carbon hexagons with respect to the edge axis, in the so-called armchair or zigzag arrangements, is distinguished spectroscopically by th...
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Veröffentlicht in: | Physical review letters 2004-12, Vol.93 (24), p.247401.1-247401.4, Article 247401 |
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creator | CANCADO, L. G PIMENTA, M. A NEVES, B. R. A DANTAS, M. S. S JORIO, A |
description | A study of step edges in graphite with different atomic structures combining Raman spectroscopy and scanning probe microscopy is presented. The orientation of the carbon hexagons with respect to the edge axis, in the so-called armchair or zigzag arrangements, is distinguished spectroscopically by the intensity of a disorder-induced Raman peak. This effect is explained by applying the double resonance theory to a semi-infinite graphite crystal and by considering the one-dimensional character of the defect. |
doi_str_mv | 10.1103/physrevlett.93.247401 |
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This effect is explained by applying the double resonance theory to a semi-infinite graphite crystal and by considering the one-dimensional character of the defect.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Exact sciences and technology</subject><subject>Fullerenes and related materials</subject><subject>Infrared and raman spectra and scattering</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Physics</subject><issn>0031-9007</issn><issn>1079-7114</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNpFkE1LAzEQhoMotlZ_grIXvW2dbLKb7FGK2kJBKXpeknTSruyXSbbQf-_WFnoaeOd5Z-Ah5J7ClFJgz9127x3uKgxhmrNpwgUHekHGFEQeC0r5JRkDMBrnAGJEbrz_AQCaZPKajGia5UKmckzmi8ZWPTYGo9ZGYYuRCm1dmsgH15vQuyFv_vOVqlUT-Q5NcOoAb5zqtmXACNcb9LfkyqrK491pTsj32-vXbB4vP94Xs5dlbDiwEFuDmaQUNVgu13mmYW3RcsokSJ5zqbTiRmuToBY8oZBxPWyESbUS1nDBJuTpeLdz7W-PPhR16Q1WlWqw7X2RiYTlnCYDmB5B41o_qLJF58pauX1BoTgoLD4HhSvcLQeFRc6Ko8Kh93B60Osa1-fWydkAPJ4A5Y2qrFONKf2Zy5hMGUvZH67CfY4</recordid><startdate>20041210</startdate><enddate>20041210</enddate><creator>CANCADO, L. 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S</au><au>JORIO, A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of the atomic structure on the Raman spectra of graphite edges</atitle><jtitle>Physical review letters</jtitle><addtitle>Phys Rev Lett</addtitle><date>2004-12-10</date><risdate>2004</risdate><volume>93</volume><issue>24</issue><spage>247401.1</spage><epage>247401.4</epage><pages>247401.1-247401.4</pages><artnum>247401</artnum><issn>0031-9007</issn><eissn>1079-7114</eissn><coden>PRLTAO</coden><abstract>A study of step edges in graphite with different atomic structures combining Raman spectroscopy and scanning probe microscopy is presented. The orientation of the carbon hexagons with respect to the edge axis, in the so-called armchair or zigzag arrangements, is distinguished spectroscopically by the intensity of a disorder-induced Raman peak. 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subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Exact sciences and technology Fullerenes and related materials Infrared and raman spectra and scattering Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Physics |
title | Influence of the atomic structure on the Raman spectra of graphite edges |
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