Interaction of Hydrated Protons with Trioctylphosphine Oxide: NMR and Theoretical Study

Interaction of trioctylphosphine oxide (TOPO) with fully ionized hydrated protons (HP) was studied in acetonitrile-d 3 and nitrobenzene-d 5 using 1H, 13C, and 31P NMR, PFG NMR, and magnetic relaxation, and the experimental results were confronted with high-precision ab initio DFT calculations. Relat...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2009-05, Vol.113 (20), p.5896-5905
Hauptverfasser:	Kříž, Jaroslav, Dybal, Jiří, Makrlík, Emanuel, Budka, Jan, Vaňura, Petr
Format:	Artikel
Sprache:	eng
Schlagworte:	A: Kinetics, Spectroscopy
Online-Zugang:	Volltext
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