Fluorous Effects in Amide-Based Receptors for Anions

Hybrid receptors designed to recognize both the sulfonate headgroup and the fluorous tail of perfluorooctanesulfonate (CF3(CF2)7SO3 −, “PFOS”) were prepared by coupling fluorinated carboxylic acids onto poly(aminomethyl)benzene scaffolds. Binding to PFOS, CF3SO3 −, p-TsO−, and Cl− was monitored by 1...

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Veröffentlicht in:Journal of organic chemistry 2009-05, Vol.74 (10), p.3706-3710
Hauptverfasser: Gavette, Jesse V, McGrath, Jacqueline M, Spuches, Anne M, Sargent, Andrew L, Allen, William E
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Sprache:eng
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