Effective Transition Probability for the Faraday Effect of Lanthanide(III) Ion Solutions

Effective Transition Probability for the Faraday Effect of Lanthanide(III) Ion Solutions

The Faraday effects of 14 lanthanide(III) ion solutions were systematically analyzed on the basis of the Faraday C term. The effective transition probability, K, which measures the magneto-optical contribution of the 4f  n → 4f  n−15d transition to the molar Verdet constant, was determined. Linear c...

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Veröffentlicht in:Journal of the American Chemical Society 2009-05, Vol.131 (18), p.6328-6329
Hauptverfasser: Miyamoto, Kayoko, Isai, Kento, Suwa, Masayori, Watarai, Hitoshi
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Isai, Kento
Suwa, Masayori
Watarai, Hitoshi
description The Faraday effects of 14 lanthanide(III) ion solutions were systematically analyzed on the basis of the Faraday C term. The effective transition probability, K, which measures the magneto-optical contribution of the 4f  n → 4f  n−15d transition to the molar Verdet constant, was determined. Linear correlations between K and the square root of the molar magnetic susceptibility of the lanthanide(III) ions, χm 1/2, were obtained. From the observed new regularity, K for promethium(III) was estimated.
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