Cation-Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(NtBu)₂]

Cation-Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(NtBu)₂]

Communication is important: The dimeric bis(imido) uranium complex [{U(NtBu)₂(I)(tBu₂bpy)}₂] (see picture; U green, N blue, I red) has cation-cation interactions between [U(NR)₂]⁺ ions. This f¹-f¹ system also displays f orbital communication between uranium(V) centers at low temperatures, and can be...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (21), p.3795-3798
Hauptverfasser: Spencer, Liam P, Schelter, Eric J, Yang, Ping, Gdula, Robyn L, Scott, Brian L, Thompson, Joe D, Kiplinger, Jaqueline L, Batista, Enrique R, Boncella, James M
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actinides
cation–cation interactions
f orbitals
imides
uranium
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container_end_page 3798
container_issue 21
container_start_page 3795
container_title Angewandte Chemie (International ed.)
container_volume 48
creator Spencer, Liam P
Schelter, Eric J
Yang, Ping
Gdula, Robyn L
Scott, Brian L
Thompson, Joe D
Kiplinger, Jaqueline L
Batista, Enrique R
Boncella, James M
description Communication is important: The dimeric bis(imido) uranium complex [{U(NtBu)₂(I)(tBu₂bpy)}₂] (see picture; U green, N blue, I red) has cation-cation interactions between [U(NR)₂]⁺ ions. This f¹-f¹ system also displays f orbital communication between uranium(V) centers at low temperatures, and can be oxidized to generate uranium(VI) bis(imido) complexes.
doi_str_mv 10.1002/anie.200806190
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subjects actinides
cation–cation interactions
f orbitals
imides
uranium
title Cation-Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(NtBu)₂]
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