A DFT Computational Study on Electrophilic Substitutions upon α-Oxy-Substituted Benzylorganolithium Compounds:  Lithium Catalysis Is the Hidden Piece of the Puzzle

A detailed DFT (B3LYP/6-31+G*) study upon α-oxybenzylorganolithium compounds such as α-carbamoyloxybenzyllithium 1 has revealed two relevant issues concerning the outcome of electrophilic substitutions (1) lithium salts catalyze these reactions, and (2) some π lithium complexes can provide an extra...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-12, Vol.126 (51), p.16738-16739
Hauptverfasser:	CAPO, Magdalena, SAA, José M
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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