Unusual Interlocking and Interpenetration Lead to Highly Porous and Robust Metal-Organic Frameworks

Stop the breathing: As the organic bridging ligands become more elaborate and large, the resulting MOFs tend to experience significant framework distortion (i.e., breathing) upon solvent removal. Rigidification of MOFs that are built from elongated tetracarboxylate bridging ligands by unusual interl...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2009-01, Vol.48 (20), p.3637-3640
Hauptverfasser:	Ma, Liqing, Lin, Wenbin
Format:	Artikel
Sprache:	eng
Schlagworte:	gas storage interlocking interpenetration Ligands metal–organic frameworks Nitrogen - chemistry Organometallic Compounds - chemistry Porosity porous materials X-Ray Diffraction
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creator	Ma, Liqing Lin, Wenbin
description	Stop the breathing: As the organic bridging ligands become more elaborate and large, the resulting MOFs tend to experience significant framework distortion (i.e., breathing) upon solvent removal. Rigidification of MOFs that are built from elongated tetracarboxylate bridging ligands by unusual interlocking and interpenetration leads to highly porous and robust hybrid materials.
doi_str_mv	10.1002/anie.200806227
format	Article
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Rigidification of MOFs that are built from elongated tetracarboxylate bridging ligands by unusual interlocking and interpenetration leads to highly porous and robust hybrid materials.</description><subject>gas storage</subject><subject>interlocking</subject><subject>interpenetration</subject><subject>Ligands</subject><subject>metal–organic frameworks</subject><subject>Nitrogen - chemistry</subject><subject>Organometallic Compounds - chemistry</subject><subject>Porosity</subject><subject>porous materials</subject><subject>X-Ray Diffraction</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkEtPwzAQhC0E4n3lCDlxS_GjjpMjQgUqFYqAnq21sy2BNC52ItR_jyEVcOO0q9W3o5kh5ITRAaOUX0BT4YBTmtOMc7VF9pnkLBVKie24D4VIVS7ZHjkI4TXyeeR2yR4rhBQZk_vEzpoudFAn46ZFXzv7VjWLBJqyP6ywwdZDW7kmmSCUSeuS22rxUq-TB-ddF77RR2e60CZ32EKdTv0imrLJtYclfjj_Fo7IzhzqgMebeUhm16Pnq9t0Mr0ZX11OUht9qhQkL6GwpcmkygtTggWJ0mTDQihQnBqFJjNIhckLIaCkylpjsrksjTIiN-KQnPe6K-_eOwytXlbBYl1Dg9GqzlTMzaWI4KAHrXcheJzrla-W4NeaUf1Vq_6qVf_UGh9ON8qdWWL5i296jEDRAx9Vjet_5PTl_Xj0V_ys_52D07DwVdCzJ06ZoCzjMWkuPgHaPo-C</recordid><startdate>20090101</startdate><enddate>20090101</enddate><creator>Ma, Liqing</creator><creator>Lin, Wenbin</creator><general>Wiley-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>FBQ</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20090101</creationdate><title>Unusual Interlocking and Interpenetration Lead to Highly Porous and Robust Metal-Organic Frameworks</title><author>Ma, Liqing ; Lin, Wenbin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4337-a52da9cdb65789bdaca5e5b64937a720b7eb6be03b8933ad07ccbb6f5db7b38b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>gas storage</topic><topic>interlocking</topic><topic>interpenetration</topic><topic>Ligands</topic><topic>metal–organic frameworks</topic><topic>Nitrogen - chemistry</topic><topic>Organometallic Compounds - chemistry</topic><topic>Porosity</topic><topic>porous materials</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Liqing</creatorcontrib><creatorcontrib>Lin, Wenbin</creatorcontrib><collection>AGRIS</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Liqing</au><au>Lin, Wenbin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unusual Interlocking and Interpenetration Lead to Highly Porous and Robust Metal-Organic Frameworks</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2009-01-01</date><risdate>2009</risdate><volume>48</volume><issue>20</issue><spage>3637</spage><epage>3640</epage><pages>3637-3640</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Stop the breathing: As the organic bridging ligands become more elaborate and large, the resulting MOFs tend to experience significant framework distortion (i.e., breathing) upon solvent removal. 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source	MEDLINE; Wiley Online Library Journals Frontfile Complete
subjects	gas storage interlocking interpenetration Ligands metal–organic frameworks Nitrogen - chemistry Organometallic Compounds - chemistry Porosity porous materials X-Ray Diffraction
title	Unusual Interlocking and Interpenetration Lead to Highly Porous and Robust Metal-Organic Frameworks
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