Total Synthesis of (−)-Incarvilline, (+)-Incarvine C, and (−)-Incarvillateine

The first total syntheses of new monoterpene alkaloids (−)-incarvilline, (+)-incarvine C, and (−)-incarvillateine, corresponding to the natural enantiomers, have been accomplished. The strategy for the synthesis of these natural products utilized 6-epi-incarvilline as a common precursor, which was a...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-12, Vol.126 (50), p.16553-16558
Hauptverfasser:	Ichikawa, Masaya, Takahashi, Masaki, Aoyagi, Sakae, Kibayashi, Chihiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds, terpenoids, prostaglandins, steroids Alkaloids - chemical synthesis Chemistry Coumaric Acids - chemistry Crystallography, X-Ray Exact sciences and technology Magnoliopsida - chemistry Models, Molecular Monoterpenes - chemical synthesis Organic chemistry Preparations and properties Stereoisomerism Terpenoids
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