Control of relative tunneling rates in single molecule bipolar electron transport
The influence of relative electron tunneling rates on electron transport in a double-barrier single-molecule junction is studied. The junction is defined by positioning a scanning tunneling microscope tip above a copper phthalocyanine molecule adsorbed on a thin oxide film grown on the NiAl(110) sur...
Gespeichert in:
Veröffentlicht in: | Physical review letters 2004-12, Vol.93 (23), p.236802.1-236802.4, Article 236802 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 236802.4 |
---|---|
container_issue | 23 |
container_start_page | 236802.1 |
container_title | Physical review letters |
container_volume | 93 |
creator | WU, S. W NAZIN, G. V CHEN, X QIU, X. H HO, W |
description | The influence of relative electron tunneling rates on electron transport in a double-barrier single-molecule junction is studied. The junction is defined by positioning a scanning tunneling microscope tip above a copper phthalocyanine molecule adsorbed on a thin oxide film grown on the NiAl(110) surface. By tuning the tip-molecule separation, the ratio of tunneling rates through the two barriers, vacuum and oxide, is controlled. This results in dramatic changes in the relative intensities of individual conduction channels, associated with different vibronic states of the molecule. |
doi_str_mv | 10.1103/physrevlett.93.236802 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_67179323</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>67179323</sourcerecordid><originalsourceid>FETCH-LOGICAL-c453t-becc0d149501da7cdf7f3b8e43c675028a9e910e4eb15ea95b78a1fd644102203</originalsourceid><addsrcrecordid>eNpFkF1L7DAQhoMoun78BCU3etd1pmmb5vKw-AULfqDXJU2nnkq26UnSBf-9OeyCVzMvPO8MPIxdIiwRQdxOf7-Dp62lGJdKLHNR1ZAfsAWCVJlELA7ZAkBgpgDkCTsN4QsAMK_qY3aCZQWIdblgrys3Ru8sdz33ZHUctsTjPI5kh_GTex0p8GHkISVLfOMsmTkt7TA5qz2nlFN_5NHrMUzOx3N21Gsb6GI_z9jH_d376jFbPz88rf6sM1OUImYtGQMdFqoE7LQ0XS970dZUCFPJEvJaK1IIVFCLJWlVtrLW2HdVUSDkOYgzdrO7O3n3b6YQm80QDFmrR3JzaCqJUolcJLDcgca7kJz1zeSHjfbfDULz32Xzkly-0XadXDZKNDuXqXe1fzC3G-p-W3t5CbjeAzoYbftkwAzhl6uElEpJ8QPfBoGU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>67179323</pqid></control><display><type>article</type><title>Control of relative tunneling rates in single molecule bipolar electron transport</title><source>American Physical Society Journals</source><creator>WU, S. W ; NAZIN, G. V ; CHEN, X ; QIU, X. H ; HO, W</creator><creatorcontrib>WU, S. W ; NAZIN, G. V ; CHEN, X ; QIU, X. H ; HO, W</creatorcontrib><description>The influence of relative electron tunneling rates on electron transport in a double-barrier single-molecule junction is studied. The junction is defined by positioning a scanning tunneling microscope tip above a copper phthalocyanine molecule adsorbed on a thin oxide film grown on the NiAl(110) surface. By tuning the tip-molecule separation, the ratio of tunneling rates through the two barriers, vacuum and oxide, is controlled. This results in dramatic changes in the relative intensities of individual conduction channels, associated with different vibronic states of the molecule.</description><identifier>ISSN: 0031-9007</identifier><identifier>EISSN: 1079-7114</identifier><identifier>DOI: 10.1103/physrevlett.93.236802</identifier><identifier>PMID: 15601185</identifier><identifier>CODEN: PRLTAO</identifier><language>eng</language><publisher>Ridge, NY: American Physical Society</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures ; Electronic transport in interface structures ; Electronic transport in mesoscopic or nanoscale materials and structures ; Electronic transport in multilayers, nanoscale materials and structures ; Exact sciences and technology ; Physics ; Tunneling</subject><ispartof>Physical review letters, 2004-12, Vol.93 (23), p.236802.1-236802.4, Article 236802</ispartof><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c453t-becc0d149501da7cdf7f3b8e43c675028a9e910e4eb15ea95b78a1fd644102203</citedby><cites>FETCH-LOGICAL-c453t-becc0d149501da7cdf7f3b8e43c675028a9e910e4eb15ea95b78a1fd644102203</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,2863,2864,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16377997$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15601185$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>WU, S. W</creatorcontrib><creatorcontrib>NAZIN, G. V</creatorcontrib><creatorcontrib>CHEN, X</creatorcontrib><creatorcontrib>QIU, X. H</creatorcontrib><creatorcontrib>HO, W</creatorcontrib><title>Control of relative tunneling rates in single molecule bipolar electron transport</title><title>Physical review letters</title><addtitle>Phys Rev Lett</addtitle><description>The influence of relative electron tunneling rates on electron transport in a double-barrier single-molecule junction is studied. The junction is defined by positioning a scanning tunneling microscope tip above a copper phthalocyanine molecule adsorbed on a thin oxide film grown on the NiAl(110) surface. By tuning the tip-molecule separation, the ratio of tunneling rates through the two barriers, vacuum and oxide, is controlled. This results in dramatic changes in the relative intensities of individual conduction channels, associated with different vibronic states of the molecule.</description><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</subject><subject>Electronic transport in interface structures</subject><subject>Electronic transport in mesoscopic or nanoscale materials and structures</subject><subject>Electronic transport in multilayers, nanoscale materials and structures</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><subject>Tunneling</subject><issn>0031-9007</issn><issn>1079-7114</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNpFkF1L7DAQhoMoun78BCU3etd1pmmb5vKw-AULfqDXJU2nnkq26UnSBf-9OeyCVzMvPO8MPIxdIiwRQdxOf7-Dp62lGJdKLHNR1ZAfsAWCVJlELA7ZAkBgpgDkCTsN4QsAMK_qY3aCZQWIdblgrys3Ru8sdz33ZHUctsTjPI5kh_GTex0p8GHkISVLfOMsmTkt7TA5qz2nlFN_5NHrMUzOx3N21Gsb6GI_z9jH_d376jFbPz88rf6sM1OUImYtGQMdFqoE7LQ0XS970dZUCFPJEvJaK1IIVFCLJWlVtrLW2HdVUSDkOYgzdrO7O3n3b6YQm80QDFmrR3JzaCqJUolcJLDcgca7kJz1zeSHjfbfDULz32Xzkly-0XadXDZKNDuXqXe1fzC3G-p-W3t5CbjeAzoYbftkwAzhl6uElEpJ8QPfBoGU</recordid><startdate>20041203</startdate><enddate>20041203</enddate><creator>WU, S. W</creator><creator>NAZIN, G. V</creator><creator>CHEN, X</creator><creator>QIU, X. H</creator><creator>HO, W</creator><general>American Physical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20041203</creationdate><title>Control of relative tunneling rates in single molecule bipolar electron transport</title><author>WU, S. W ; NAZIN, G. V ; CHEN, X ; QIU, X. H ; HO, W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c453t-becc0d149501da7cdf7f3b8e43c675028a9e910e4eb15ea95b78a1fd644102203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures</topic><topic>Electronic transport in interface structures</topic><topic>Electronic transport in mesoscopic or nanoscale materials and structures</topic><topic>Electronic transport in multilayers, nanoscale materials and structures</topic><topic>Exact sciences and technology</topic><topic>Physics</topic><topic>Tunneling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>WU, S. W</creatorcontrib><creatorcontrib>NAZIN, G. V</creatorcontrib><creatorcontrib>CHEN, X</creatorcontrib><creatorcontrib>QIU, X. H</creatorcontrib><creatorcontrib>HO, W</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Physical review letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>WU, S. W</au><au>NAZIN, G. V</au><au>CHEN, X</au><au>QIU, X. H</au><au>HO, W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Control of relative tunneling rates in single molecule bipolar electron transport</atitle><jtitle>Physical review letters</jtitle><addtitle>Phys Rev Lett</addtitle><date>2004-12-03</date><risdate>2004</risdate><volume>93</volume><issue>23</issue><spage>236802.1</spage><epage>236802.4</epage><pages>236802.1-236802.4</pages><artnum>236802</artnum><issn>0031-9007</issn><eissn>1079-7114</eissn><coden>PRLTAO</coden><abstract>The influence of relative electron tunneling rates on electron transport in a double-barrier single-molecule junction is studied. The junction is defined by positioning a scanning tunneling microscope tip above a copper phthalocyanine molecule adsorbed on a thin oxide film grown on the NiAl(110) surface. By tuning the tip-molecule separation, the ratio of tunneling rates through the two barriers, vacuum and oxide, is controlled. This results in dramatic changes in the relative intensities of individual conduction channels, associated with different vibronic states of the molecule.</abstract><cop>Ridge, NY</cop><pub>American Physical Society</pub><pmid>15601185</pmid><doi>10.1103/physrevlett.93.236802</doi><tpages>1</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0031-9007 |
ispartof | Physical review letters, 2004-12, Vol.93 (23), p.236802.1-236802.4, Article 236802 |
issn | 0031-9007 1079-7114 |
language | eng |
recordid | cdi_proquest_miscellaneous_67179323 |
source | American Physical Society Journals |
subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures Electronic transport in interface structures Electronic transport in mesoscopic or nanoscale materials and structures Electronic transport in multilayers, nanoscale materials and structures Exact sciences and technology Physics Tunneling |
title | Control of relative tunneling rates in single molecule bipolar electron transport |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-29T23%3A59%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Control%20of%20relative%20tunneling%20rates%20in%20single%20molecule%20bipolar%20electron%20transport&rft.jtitle=Physical%20review%20letters&rft.au=WU,%20S.%20W&rft.date=2004-12-03&rft.volume=93&rft.issue=23&rft.spage=236802.1&rft.epage=236802.4&rft.pages=236802.1-236802.4&rft.artnum=236802&rft.issn=0031-9007&rft.eissn=1079-7114&rft.coden=PRLTAO&rft_id=info:doi/10.1103/physrevlett.93.236802&rft_dat=%3Cproquest_cross%3E67179323%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=67179323&rft_id=info:pmid/15601185&rfr_iscdi=true |