pH-Selective Synthesis and Structures of Alkynyl, Acyl, and Ketonyl Intermediates in Anti-Markovnikov and Markovnikov Hydrations of a Terminal Alkyne with a Water-Soluble Iridium Aqua Complex in Water

Chemoselective synthesis and isolation of alkynyl [Cp*IrIII(bpy)CCPh]+ (2, Cp* = η5-C5Me5, bpy = 2,2‘-bipyridine), acyl [Cp*IrIII(bpy)C(O)CH2Ph]+ (3), and ketonyl [Cp*IrIII(bpy)CH2C(O)Ph]+ (4) intermediates in anti-Markovnikov and Markovnikov hydration of phenylacetylene in water have been achieved...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-12, Vol.126 (50), p.16520-16527
Hauptverfasser:	Ogo, Seiji, Uehara, Keiji, Abura, Tsutomu, Watanabe, Yoshihito, Fukuzumi, Shunichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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