Detection of buried microstructures by nonlinear light scattering spectroscopy

Many processes in chemistry and physics rely on the structure, growth or change of material buried in solids. The impenetrable surrounding medium often prohibits the study of such material in situ. Nonlinear light scattering can be used to observe the internal structure of a crystalline state embedd...

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Veröffentlicht in:Physical review letters 2009-03, Vol.102 (9), p.095502-095502, Article 095502
Hauptverfasser: de Beer, A G F, de Aguiar, H B, Nijsen, J F W, Roke, S
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creator de Beer, A G F
de Aguiar, H B
Nijsen, J F W
Roke, S
description Many processes in chemistry and physics rely on the structure, growth or change of material buried in solids. The impenetrable surrounding medium often prohibits the study of such material in situ. Nonlinear light scattering can be used to observe the internal structure of a crystalline state embedded inside another solid state. Vibrational sum frequency scattering patterns of polymer microspheres, consisting of both amorphous and crystalline material, reveal the size of the buried microstructure and the optical components of the second-order susceptibility of the material. The vibrational spectra reveal the molecular structure.
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source MEDLINE; American Physical Society Journals
subjects Crystallization
Lactic Acid - chemistry
Light
Models, Chemical
Nonlinear Dynamics
Polyesters
Polymers - chemistry
Scattering, Radiation
Spectrum Analysis - methods
X-Ray Diffraction
title Detection of buried microstructures by nonlinear light scattering spectroscopy
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