Detection of buried microstructures by nonlinear light scattering spectroscopy
Many processes in chemistry and physics rely on the structure, growth or change of material buried in solids. The impenetrable surrounding medium often prohibits the study of such material in situ. Nonlinear light scattering can be used to observe the internal structure of a crystalline state embedd...
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Veröffentlicht in: | Physical review letters 2009-03, Vol.102 (9), p.095502-095502, Article 095502 |
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creator | de Beer, A G F de Aguiar, H B Nijsen, J F W Roke, S |
description | Many processes in chemistry and physics rely on the structure, growth or change of material buried in solids. The impenetrable surrounding medium often prohibits the study of such material in situ. Nonlinear light scattering can be used to observe the internal structure of a crystalline state embedded inside another solid state. Vibrational sum frequency scattering patterns of polymer microspheres, consisting of both amorphous and crystalline material, reveal the size of the buried microstructure and the optical components of the second-order susceptibility of the material. The vibrational spectra reveal the molecular structure. |
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The impenetrable surrounding medium often prohibits the study of such material in situ. Nonlinear light scattering can be used to observe the internal structure of a crystalline state embedded inside another solid state. Vibrational sum frequency scattering patterns of polymer microspheres, consisting of both amorphous and crystalline material, reveal the size of the buried microstructure and the optical components of the second-order susceptibility of the material. The vibrational spectra reveal the molecular structure.</description><subject>Crystallization</subject><subject>Lactic Acid - chemistry</subject><subject>Light</subject><subject>Models, Chemical</subject><subject>Nonlinear Dynamics</subject><subject>Polyesters</subject><subject>Polymers - chemistry</subject><subject>Scattering, Radiation</subject><subject>Spectrum Analysis - methods</subject><subject>X-Ray Diffraction</subject><issn>0031-9007</issn><issn>1079-7114</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpNkE1Lw0AQhhdRbK3-hbInb6kz2eZjj1I_oaiInkN2M9uupEnc3Qj596a0oKeB4XnfYR7G5ggLRBA3b9vBv9PPmkJYIMQLkEkC8QmbImQyyhCXp2wKIDCSANmEXXj_BQAYp_k5m6AUMk4ETtnLHQXSwbYNbw1XvbNU8Z3VrvXB9Tr0jjxXA2_aprYNlY7XdrMN3OsyBHK22XDfjQUjr9tuuGRnpqw9XR3njH0-3H-snqL16-Pz6nYdaQEyRAKWUisUZU6iEnlcVYKkyVWZQZ4pU6XagBEqrwzIpaacMhMbjHNQyqBIUMzY9aG3c-13Tz4UO-s11XXZUNv7Is0wFWkGI5gewP1H3pEpOmd3pRsKhGJvsvhnctzFxcHkGJwfL_RqR9Vf7KhO_AIEBXTJ</recordid><startdate>20090306</startdate><enddate>20090306</enddate><creator>de Beer, A G F</creator><creator>de Aguiar, H B</creator><creator>Nijsen, J F W</creator><creator>Roke, S</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20090306</creationdate><title>Detection of buried microstructures by nonlinear light scattering spectroscopy</title><author>de Beer, A G F ; de Aguiar, H B ; Nijsen, J F W ; Roke, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c309t-3049cb13a8e3d382dd3e9f8ba7087bfd6cf0f3b8df094ce8e7f2f1280bbf13513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Crystallization</topic><topic>Lactic Acid - chemistry</topic><topic>Light</topic><topic>Models, Chemical</topic><topic>Nonlinear Dynamics</topic><topic>Polyesters</topic><topic>Polymers - chemistry</topic><topic>Scattering, Radiation</topic><topic>Spectrum Analysis - methods</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>de Beer, A G F</creatorcontrib><creatorcontrib>de Aguiar, H B</creatorcontrib><creatorcontrib>Nijsen, J F W</creatorcontrib><creatorcontrib>Roke, S</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Physical review letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Beer, A G F</au><au>de Aguiar, H B</au><au>Nijsen, J F W</au><au>Roke, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Detection of buried microstructures by nonlinear light scattering spectroscopy</atitle><jtitle>Physical review letters</jtitle><addtitle>Phys Rev Lett</addtitle><date>2009-03-06</date><risdate>2009</risdate><volume>102</volume><issue>9</issue><spage>095502</spage><epage>095502</epage><pages>095502-095502</pages><artnum>095502</artnum><issn>0031-9007</issn><eissn>1079-7114</eissn><abstract>Many processes in chemistry and physics rely on the structure, growth or change of material buried in solids. 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subjects | Crystallization Lactic Acid - chemistry Light Models, Chemical Nonlinear Dynamics Polyesters Polymers - chemistry Scattering, Radiation Spectrum Analysis - methods X-Ray Diffraction |
title | Detection of buried microstructures by nonlinear light scattering spectroscopy |
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