Unprecedented Solvent‐Assisted Reactivity of Hydrido W3CuS4 Cubane Clusters: The Non‐Innocent Behaviour of the Cluster‐Core Unit

Opening the cluster core: Substitution of the chloride ligand in the novel cationic cluster [W3CuS4H3Cl(dmpe)3]+ (see figure; dmpe=1,2‐bis(dimethylphosphino)ethane) by acetonitrile is promoted by water addition. Kinetic and density functional theory studies lead to a mechanistic proposal in which ac...

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Veröffentlicht in:	Chemistry : a European journal 2009-01, Vol.15 (18), p.4582-4594
Hauptverfasser:	Algarra, Andrés G., Feliz, Marta, Fernández‐Trujillo, M. Jesús, Llusar, Rosa, Safont, Vicent S., Vicent, Cristian, Basallote, Manuel G.
Format:	Artikel
Sprache:	eng
Schlagworte:	cluster compounds copper Copper - chemistry Crystallography, X-Ray density functional calculations Electron Spin Resonance Spectroscopy Kinetics Molecular Structure Thermodynamics tungsten Tungsten Compounds - chemical synthesis Tungsten Compounds - chemistry
Online-Zugang:	Volltext
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