Luminescent Heteropolynuclear Complexes of 3,5‐Dimethylpyrazolate [Pt2Au2M2(Me2pz)8] (M=Ag, Cu) Showing the Synergistic Effect of Three Transition Elements in the Excited State
Swap the coins! The Pt2Au2, Pt2Au2Cu2, and Pt2Au2Ag2 complexes of 3,5‐dimethylpyrazolate exhibit yellow‐green, orange, and sky‐blue luminescence, respectively (see figure). The emission energies of Pt2Au2M2 complexes can be controlled by the change of the third coinage metal ions M. The Pt2Au2M2 com...
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| Veröffentlicht in: | Chemistry : a European journal 2009-01, Vol.15 (17), p.4238-4242 |
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| container_title | Chemistry : a European journal |
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| creator | Umakoshi, Keisuke Saito, Keizo Arikawa, Yasuhiro Onishi, Masayoshi Ishizaka, Shoji Kitamura, Noboru Nakao, Yoshihide Sakaki, Shigeyoshi |
| description | Swap the coins! The Pt2Au2, Pt2Au2Cu2, and Pt2Au2Ag2 complexes of 3,5‐dimethylpyrazolate exhibit yellow‐green, orange, and sky‐blue luminescence, respectively (see figure). The emission energies of Pt2Au2M2 complexes can be controlled by the change of the third coinage metal ions M. The Pt2Au2M2 complexes take the cis configuration with respect to the Au2M2 plane.
Swap the coins! The Pt2Au2, Pt2Au2Cu2, and Pt2Au2Ag2 complexes of 3,5‐dimethylpyrazolate exhibit yellow‐green, orange, and sky‐blue luminescence, respectively (see figure). The emission energies of Pt2Au2M2 complexes can be controlled by the change of the third coinage metal ions M. The Pt2Au2M2 complexes take the cis configuration with respect to the Au2M2 plane. |
| doi_str_mv | 10.1002/chem.200900290 |
| format | Article |
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Swap the coins! The Pt2Au2, Pt2Au2Cu2, and Pt2Au2Ag2 complexes of 3,5‐dimethylpyrazolate exhibit yellow‐green, orange, and sky‐blue luminescence, respectively (see figure). The emission energies of Pt2Au2M2 complexes can be controlled by the change of the third coinage metal ions M. The Pt2Au2M2 complexes take the cis configuration with respect to the Au2M2 plane.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.200900290</identifier><identifier>PMID: 19283817</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag</publisher><subject>coinage metals ; luminescence ; metal–metal interactions ; N ligands ; platinum</subject><ispartof>Chemistry : a European journal, 2009-01, Vol.15 (17), p.4238-4242</ispartof><rights>Copyright © 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3830-c0d51e81f1b7238e983fafc2cf235c6f94637a8a591f5abd343bdb37e6c330253</citedby><cites>FETCH-LOGICAL-c3830-c0d51e81f1b7238e983fafc2cf235c6f94637a8a591f5abd343bdb37e6c330253</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.200900290$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.200900290$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19283817$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Umakoshi, Keisuke</creatorcontrib><creatorcontrib>Saito, Keizo</creatorcontrib><creatorcontrib>Arikawa, Yasuhiro</creatorcontrib><creatorcontrib>Onishi, Masayoshi</creatorcontrib><creatorcontrib>Ishizaka, Shoji</creatorcontrib><creatorcontrib>Kitamura, Noboru</creatorcontrib><creatorcontrib>Nakao, Yoshihide</creatorcontrib><creatorcontrib>Sakaki, Shigeyoshi</creatorcontrib><title>Luminescent Heteropolynuclear Complexes of 3,5‐Dimethylpyrazolate [Pt2Au2M2(Me2pz)8] (M=Ag, Cu) Showing the Synergistic Effect of Three Transition Elements in the Excited State</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Swap the coins! The Pt2Au2, Pt2Au2Cu2, and Pt2Au2Ag2 complexes of 3,5‐dimethylpyrazolate exhibit yellow‐green, orange, and sky‐blue luminescence, respectively (see figure). The emission energies of Pt2Au2M2 complexes can be controlled by the change of the third coinage metal ions M. The Pt2Au2M2 complexes take the cis configuration with respect to the Au2M2 plane.
Swap the coins! The Pt2Au2, Pt2Au2Cu2, and Pt2Au2Ag2 complexes of 3,5‐dimethylpyrazolate exhibit yellow‐green, orange, and sky‐blue luminescence, respectively (see figure). The emission energies of Pt2Au2M2 complexes can be controlled by the change of the third coinage metal ions M. The Pt2Au2M2 complexes take the cis configuration with respect to the Au2M2 plane.</description><subject>coinage metals</subject><subject>luminescence</subject><subject>metal–metal interactions</subject><subject>N ligands</subject><subject>platinum</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u00AQxy0EoqFw5Yj2hFqpDvsRfx16iIxLkBKBlHBCyFqvZ-NFa6_ZXat1TzxCn4VH4klwSESPnEYj_eY3o_kHwWuC5wRj-k400M4pxtnUZPhJMCMRJSFL4uhpMMPZIgnjiGVnwQvnvuMJixl7HpyRjKYsJcks-LUeWtWBE9B5tAIP1vRGj90gNHCLctP2Gu7AISMRu4p-_3x4r1rwzaj70fJ7o7kH9PWzp8uBbujFBmh_f5l-Qxeb6-X-CuXDJdo25lZ1e-QbQNuxA7tXziuBCilB-IN411gAtLO8c8or06FCQzsd5JDq_o4Vd0J5qNHWT-teBs8k1w5enep58OWm2OWrcP3pw8d8uQ4FSxkOBa4jAimRpEooSyFLmeRSUCEpi0Qss0XMEp7yKCMy4lXNFqyqK5ZALBjDNGLnwdujt7fmxwDOl62a_qQ178AMrowTskhZFE_g_AgKa5yzIMveqpbbsSS4PKRUHlIq_6U0Dbw5mYeqhfoRP8UyAdkRuFUaxv_oynxVbB7lfwC026EU</recordid><startdate>20090101</startdate><enddate>20090101</enddate><creator>Umakoshi, Keisuke</creator><creator>Saito, Keizo</creator><creator>Arikawa, Yasuhiro</creator><creator>Onishi, Masayoshi</creator><creator>Ishizaka, Shoji</creator><creator>Kitamura, Noboru</creator><creator>Nakao, Yoshihide</creator><creator>Sakaki, Shigeyoshi</creator><general>WILEY‐VCH Verlag</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20090101</creationdate><title>Luminescent Heteropolynuclear Complexes of 3,5‐Dimethylpyrazolate [Pt2Au2M2(Me2pz)8] (M=Ag, Cu) Showing the Synergistic Effect of Three Transition Elements in the Excited State</title><author>Umakoshi, Keisuke ; Saito, Keizo ; Arikawa, Yasuhiro ; Onishi, Masayoshi ; Ishizaka, Shoji ; Kitamura, Noboru ; Nakao, Yoshihide ; Sakaki, Shigeyoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3830-c0d51e81f1b7238e983fafc2cf235c6f94637a8a591f5abd343bdb37e6c330253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>coinage metals</topic><topic>luminescence</topic><topic>metal–metal interactions</topic><topic>N ligands</topic><topic>platinum</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Umakoshi, Keisuke</creatorcontrib><creatorcontrib>Saito, Keizo</creatorcontrib><creatorcontrib>Arikawa, Yasuhiro</creatorcontrib><creatorcontrib>Onishi, Masayoshi</creatorcontrib><creatorcontrib>Ishizaka, Shoji</creatorcontrib><creatorcontrib>Kitamura, Noboru</creatorcontrib><creatorcontrib>Nakao, Yoshihide</creatorcontrib><creatorcontrib>Sakaki, Shigeyoshi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Umakoshi, Keisuke</au><au>Saito, Keizo</au><au>Arikawa, Yasuhiro</au><au>Onishi, Masayoshi</au><au>Ishizaka, Shoji</au><au>Kitamura, Noboru</au><au>Nakao, Yoshihide</au><au>Sakaki, Shigeyoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Luminescent Heteropolynuclear Complexes of 3,5‐Dimethylpyrazolate [Pt2Au2M2(Me2pz)8] (M=Ag, Cu) Showing the Synergistic Effect of Three Transition Elements in the Excited State</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2009-01-01</date><risdate>2009</risdate><volume>15</volume><issue>17</issue><spage>4238</spage><epage>4242</epage><pages>4238-4242</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Swap the coins! The Pt2Au2, Pt2Au2Cu2, and Pt2Au2Ag2 complexes of 3,5‐dimethylpyrazolate exhibit yellow‐green, orange, and sky‐blue luminescence, respectively (see figure). The emission energies of Pt2Au2M2 complexes can be controlled by the change of the third coinage metal ions M. The Pt2Au2M2 complexes take the cis configuration with respect to the Au2M2 plane.
Swap the coins! The Pt2Au2, Pt2Au2Cu2, and Pt2Au2Ag2 complexes of 3,5‐dimethylpyrazolate exhibit yellow‐green, orange, and sky‐blue luminescence, respectively (see figure). The emission energies of Pt2Au2M2 complexes can be controlled by the change of the third coinage metal ions M. The Pt2Au2M2 complexes take the cis configuration with respect to the Au2M2 plane.</abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag</pub><pmid>19283817</pmid><doi>10.1002/chem.200900290</doi><tpages>5</tpages></addata></record> |
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| subjects | coinage metals luminescence metal–metal interactions N ligands platinum |
| title | Luminescent Heteropolynuclear Complexes of 3,5‐Dimethylpyrazolate [Pt2Au2M2(Me2pz)8] (M=Ag, Cu) Showing the Synergistic Effect of Three Transition Elements in the Excited State |
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