Bis(tetra-n-butylammonium) (μ-N,N′-diselenium dinitride)bis[tribromopalladate(II)]
The reaction of Se4N4 with (Bu4N)2[Pd2Br6] gives the title compound, (C16H36N)2[Pd2Br6(N2Se2)], in good yield. The [Pd2(Se2N2)Br6]2− anion lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The crystal structure confirms the coordination of the Se2N2 unit to...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2004-12, Vol.60 (12), p.m643-m644 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 60 |
| creator | Aucott, Stephen M. Dale, Sophie H. Elsegood, Mark R. J. Holmes, Kathryn E. James, Sarah L. M. Kelly, Paul F. |
| description | The reaction of Se4N4 with (Bu4N)2[Pd2Br6] gives the title compound, (C16H36N)2[Pd2Br6(N2Se2)], in good yield. The [Pd2(Se2N2)Br6]2− anion lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The crystal structure confirms the coordination of the Se2N2 unit to Pd through the N atoms, as previously assigned by IR spectroscopic analysis [Kelly, Slawin & Soriano‐Rama (1997). J. Chem. Soc. Dalton Trans. pp. 559–562]. The title compound contains the longest Pd—N bond so far observed for such systems. |
| doi_str_mv | 10.1107/S0108270104027040 |
| format | Article |
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The title compound contains the longest Pd—N bond so far observed for such systems.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Crystalline state (including molecular motions in solids)</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Theory of crystal structure, crystal symmetry; calculations and modeling</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkc-O0zAQxi0EYsvCA3BBewG1EoaZ2I6T47aCpdIShAAhhJDlOI5kyJ9iJ4LeeKFeOHPqA_AQPAmOWrEHDnvx2J7f9409Q8h9hCeIIJ--AYQskXHlEAOHG2SGKQAVUuQ3yWxK0yl_Qu6E8BkAkiRht8kJCiHzXLAZ0UsX9rv5YAevaUfLcdg2-51u275zY7s4m__-RYvHxZ8fP2nlgm3sdH1Wuc4N3lV2sd-Vk8HHeIpb37f9frfRTaMrPdj5er34dJfcqnUT7L1jPCXvnj97u3pBL19drFfnl9TwHJCWQssqtbYsEbQsTcVLIzmkUHGGzBhkmEFq0CLLjK1SU2ueJiJjNUtkKTk7JY8Ovhvffx1tGFTrgrHxKZ3tx6BSiVyy-OnrwCTWwVTKCOIBNL4Pwdtabbxrtd8qBDUNQP03gKh5cDQfy9ZWV4pjxyPw8AjoYHRTe90ZF664lHEQLI9cduC-ucZur6-szj-sli9R5Bil9CB1YbDf_0m1_xKbwKRQ74sLVeTL15jloAr2F4wNsZ0</recordid><startdate>200412</startdate><enddate>200412</enddate><creator>Aucott, Stephen M.</creator><creator>Dale, Sophie H.</creator><creator>Elsegood, Mark R. 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M.</au><au>Kelly, Paul F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bis(tetra-n-butylammonium) (μ-N,N′-diselenium dinitride)bis[tribromopalladate(II)]</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2004-12</date><risdate>2004</risdate><volume>60</volume><issue>12</issue><spage>m643</spage><epage>m644</epage><pages>m643-m644</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><coden>ACSCEE</coden><abstract>The reaction of Se4N4 with (Bu4N)2[Pd2Br6] gives the title compound, (C16H36N)2[Pd2Br6(N2Se2)], in good yield. The [Pd2(Se2N2)Br6]2− anion lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The crystal structure confirms the coordination of the Se2N2 unit to Pd through the N atoms, as previously assigned by IR spectroscopic analysis [Kelly, Slawin & Soriano‐Rama (1997). J. Chem. Soc. Dalton Trans. pp. 559–562]. 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| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2004-12, Vol.60 (12), p.m643-m644 |
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| source | Access via Wiley Online Library; Alma/SFX Local Collection |
| subjects | Condensed matter: structure, mechanical and thermal properties Crystalline state (including molecular motions in solids) Exact sciences and technology Physics Structure of solids and liquids crystallography Structure of specific crystalline solids Theory of crystal structure, crystal symmetry calculations and modeling |
| title | Bis(tetra-n-butylammonium) (μ-N,N′-diselenium dinitride)bis[tribromopalladate(II)] |
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