Oxidation Reactivity of Bis(μ-oxo) Dinickel(III) Complexes: Arene Hydroxylation of the Supporting Ligand
In the nick(el) of time: Bis(μ-oxo) dinickel(III) complexes 2 (see scheme), generated in the reaction of 1 with H₂O₂, are capable of hydroxylating the xylyl linker of the supporting ligand to give 3. Kinetic studies reveal that hydroxylation proceeds by electrophilic aromatic substitution. The lower...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2009-01, Vol.48 (18), p.3304-3307 |
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| container_title | Angewandte Chemie (International ed.) |
| container_volume | 48 |
| creator | Honda, Kaoru Cho, Jaeheung Matsumoto, Takahiro Roh, Jungyun Furutachi, Hideki Tosha, Takehiko Kubo, Minoru Fujinami, Shuhei Ogura, Takashi Kitagawa, Teizo Suzuki, Masatatsu |
| description | In the nick(el) of time: Bis(μ-oxo) dinickel(III) complexes 2 (see scheme), generated in the reaction of 1 with H₂O₂, are capable of hydroxylating the xylyl linker of the supporting ligand to give 3. Kinetic studies reveal that hydroxylation proceeds by electrophilic aromatic substitution. The lower reactivity than the corresponding μ-η²:η²-peroxo dicopper(II) complexes can be attributed to unfavorable entropy effects. |
| doi_str_mv | 10.1002/anie.200900222 |
| format | Article |
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The lower reactivity than the corresponding μ-η²:η²-peroxo dicopper(II) complexes can be attributed to unfavorable entropy effects.</description><subject>Hydroxylation</subject><subject>kinetics</subject><subject>Ligands</subject><subject>nickel</subject><subject>Nickel - chemistry</subject><subject>Organometallic Compounds - chemistry</subject><subject>oxidation</subject><subject>Oxidation-Reduction</subject><subject>reaction mechanisms</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkMFu1DAURS1ERUthyxK8Qu0ig5_txEl3w1BopBGVaFlbTvIyGDJxsDMw-Te-gW_CVUYtu65sS-ceWYeQV8AWwBh_Z3qLC85YER-cPyEnkHJIhFLiabxLIRKVp3BMnofwPSJ5zrJn5BgKIVUB4oTY671tzGhdT7-gqUf7y44TdS19b8PZ3z-J27tz-sH2tv6B3VlZlud05bZDh3sMF3TpsUd6NTXe7adu1sTt-A3pzW4YnB9tv6FruzF984IctaYL-PJwnpLbj5e3q6tkff2pXC3XSR1_yxPOTZbmUAFC25iMi6rmRsqKYWHaBmRbi6JpmMmYkqhQ1hUaCYIbBalKU3FK3s7awbufOwyj3tpQY9eZHt0u6EyBTAEggosZrL0LwWOrB2-3xk8amL5rq-_a6vu2cfD6YN5VW2we8EPMCBQz8Nt2OD2i08vP5eX_8jfztjVOm423QX-94QwEg9iA55n4B4Wvj8k</recordid><startdate>20090101</startdate><enddate>20090101</enddate><creator>Honda, Kaoru</creator><creator>Cho, Jaeheung</creator><creator>Matsumoto, Takahiro</creator><creator>Roh, Jungyun</creator><creator>Furutachi, Hideki</creator><creator>Tosha, Takehiko</creator><creator>Kubo, Minoru</creator><creator>Fujinami, Shuhei</creator><creator>Ogura, Takashi</creator><creator>Kitagawa, Teizo</creator><creator>Suzuki, Masatatsu</creator><general>Wiley-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>FBQ</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20090101</creationdate><title>Oxidation Reactivity of Bis(μ-oxo) Dinickel(III) Complexes: Arene Hydroxylation of the Supporting Ligand</title><author>Honda, Kaoru ; Cho, Jaeheung ; Matsumoto, Takahiro ; Roh, Jungyun ; Furutachi, Hideki ; Tosha, Takehiko ; Kubo, Minoru ; Fujinami, Shuhei ; Ogura, Takashi ; Kitagawa, Teizo ; Suzuki, Masatatsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4332-22a6581b1e1fda623bc2a44b0e9afd14fc39dd0a6074e7e4cbea4132a7157553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Hydroxylation</topic><topic>kinetics</topic><topic>Ligands</topic><topic>nickel</topic><topic>Nickel - chemistry</topic><topic>Organometallic Compounds - chemistry</topic><topic>oxidation</topic><topic>Oxidation-Reduction</topic><topic>reaction mechanisms</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Honda, Kaoru</creatorcontrib><creatorcontrib>Cho, Jaeheung</creatorcontrib><creatorcontrib>Matsumoto, Takahiro</creatorcontrib><creatorcontrib>Roh, Jungyun</creatorcontrib><creatorcontrib>Furutachi, Hideki</creatorcontrib><creatorcontrib>Tosha, Takehiko</creatorcontrib><creatorcontrib>Kubo, Minoru</creatorcontrib><creatorcontrib>Fujinami, Shuhei</creatorcontrib><creatorcontrib>Ogura, Takashi</creatorcontrib><creatorcontrib>Kitagawa, Teizo</creatorcontrib><creatorcontrib>Suzuki, Masatatsu</creatorcontrib><collection>AGRIS</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Honda, Kaoru</au><au>Cho, Jaeheung</au><au>Matsumoto, Takahiro</au><au>Roh, Jungyun</au><au>Furutachi, Hideki</au><au>Tosha, Takehiko</au><au>Kubo, Minoru</au><au>Fujinami, Shuhei</au><au>Ogura, Takashi</au><au>Kitagawa, Teizo</au><au>Suzuki, Masatatsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxidation Reactivity of Bis(μ-oxo) Dinickel(III) Complexes: Arene Hydroxylation of the Supporting Ligand</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2009-01-01</date><risdate>2009</risdate><volume>48</volume><issue>18</issue><spage>3304</spage><epage>3307</epage><pages>3304-3307</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>In the nick(el) of time: Bis(μ-oxo) dinickel(III) complexes 2 (see scheme), generated in the reaction of 1 with H₂O₂, are capable of hydroxylating the xylyl linker of the supporting ligand to give 3. 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| subjects | Hydroxylation kinetics Ligands nickel Nickel - chemistry Organometallic Compounds - chemistry oxidation Oxidation-Reduction reaction mechanisms |
| title | Oxidation Reactivity of Bis(μ-oxo) Dinickel(III) Complexes: Arene Hydroxylation of the Supporting Ligand |
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