Matrix reorganization with intramolecular tunneling of H atom: formic acid in Ar matrix

The intramolecular tunneling of hydrogen atom in formic acid HCOOH at low temperatures is considered based on literature experimental data on C-O internal rotation. The energetic and geometric parameters as well as vibrational frequencies for formic acid in cis and trans configurations surrounded by...

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Veröffentlicht in:	The Journal of chemical physics 2009-04, Vol.130 (14), p.144502-144502
Hauptverfasser:	Trakhtenberg, Leonid I, Fokeyev, Anatoly A, Zyubin, Alexander S, Mebel, Alexander M, Lin, S H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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