Direct Access to Ketones from Aldehydes via Rhodium-Catalyzed Cross-Coupling Reaction with Potassium Trifluoro(organo)borates

A direct cross-coupling reaction of aromatic aldehydes with potassium trifluoro(organo)borates afforded ketones in high yields and under mild conditions in the presence of a rhodium catalyst and acetone. This new reaction, involving a formal aldehyde C−H bond activation, is believed to proceed via a...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-12, Vol.126 (47), p.15356-15357
Hauptverfasser:	Pucheault, Mathieu, Darses, Sylvain, Genet, Jean-Pierre
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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