Highly Diastereoselective Tandem Photoenolization−Hetero-Diels−Alder Cycloaddition Reactions of o-Tolualdehydes in the Solid State

The (E)-photoenols generated in situ by photolysis of o-tolualdehydes 1−5 in the solid state react with the precursor aldehydes as dienophiles in a hetero-Diels−Alder cycloaddition fashion to afford trans-3-arylisochromanols in excellent yields and in a high diastereoselectivity. An examination of t...

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Veröffentlicht in:	Journal of organic chemistry 2004-11, Vol.69 (24), p.8459-8466
Hauptverfasser:	Moorthy, Jarugu Narasimha, Mal, Prasenjit, Singhal, Nidhi, Venkatakrishnan, Parthasarathi, Malik, Ravish, Venugopalan, Paloth
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Online-Zugang:	Volltext
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